Differentiated Di- and Polyboron Compounds: Synthesis and Application in Successive Suzuki-Miyaura Coupling

被引：16
作者：
Xu, Liang
Li, Pengfei [1 ]
机构：
[1] Xi An Jiao Tong Univ, Ctr Organ Chem, FIST, Xian 710054, Shaanxi, Peoples R China
来源：
SYNLETT | 2014年 / 25卷 / 13期
基金：
美国国家科学基金会;
关键词：
polyboron; selective coupling; C-H borylation; modular synthesis; SINGLE AROMATIC SUBSTRATE; SMALL-MOLECULE SYNTHESIS; C-H BORYLATION; MULTISUBSTITUTED OLEFINS; SELECTIVE SYNTHESIS; GENERAL-SOLUTION; BORON REAGENTS; ACTIVATION; STRATEGY; ACIDS;
D O I：
10.1055/s-0033-1339114
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Differentiated polyboron compounds have emerged as powerful building blocks for modular assembly of complex molecules through selective Suzuki-Miyaura coupling (SMC). Recent progress in this area is briefly reviewed. A novel methodology involving iridium-catalyzed C-H borylation and highly selective SMC toward synthesis and application of this type of building blocks is discussed.
引用
收藏
页码：1799 / 1802
页数：4
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