Viscosity coefficients of KCl, NaCl, NaI, KNO3, LiNO3, NaBPh4 and Bu4NI in water-rich binary mixtures containing propan-2-ol at 298.15 K

被引:1
作者
Bald, Adam [1 ]
Kinart, Zdzislaw [1 ]
机构
[1] Univ Lodz, Dept Phys Chem, Fac Chem, Lodz, Poland
关键词
Viscosity of solutions; water + propan-2-ol mixtures; Jones-Dole equation; viscosity B-coefficients; JONES-DOLE EQUATION; BUTYL ALCOHOL MIXTURES; AQUEOUS-SOLUTIONS; B-COEFFICIENT; IONIC ASSOCIATION; DICARBOXYLIC-ACIDS; SALTS; CACL2; 26-DEGREES-C; PROPAN-1-OL;
D O I
10.1080/00319104.2016.1218491
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Viscosities of KCl, NaCl, NaI, KNO3, LiNO3, NaBPh4 and Bu4NI solutions (from similar to 0.01M to similar to 0.05M) in water (1) + propan-2-ol) (2) binary mixtures with mole fractions of propan-2-ol, x(2)=0.01, 0.02, 0.05, 0.075, 0.10 and 0.15, were determined at 298. 15K. The relative viscosity data have been analysed and interpreted in terms of the Jones-Dole equation, (r)=A.c(1/2)+B.c. The obtained results allowed to determine the values of B-+/- coefficients for individual ions using the assumption about the equality. All the results presented in this article have been discussed in terms of ion-solvent interactions.
引用
收藏
页码:386 / 395
页数:10
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