Characterisation of archaeological wood: A case study on the deterioration of a coffin

被引:24
作者
Crestini, Claudia [1 ]
El Hadidi, Nesrin M. N. [2 ]
Palleschi, Giuseppe [1 ]
机构
[1] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, I-00133 Rome, Italy
[2] Cairo Univ, Conservat Dept, Fac Archaeol, Giza 12613, Egypt
关键词
Archaeological wood characterisation; Lignin structure; P-31-NMR; 2D-NMR; Scanning electron microscopy; ANALYTICAL PYROLYSIS; NMR; LIGNIN; SPECTROSCOPY;
D O I
10.1016/j.microc.2009.03.003
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An advanced strategy for the improvement of conservation techniques applied to archaeological wood requires a deep insight in its structure. The authors report here a new approach to the structural characterisation of ancient wood. A sample of an ancient Egyptian artefact was studied by means of scanning electron microscopy, quantitation of the residual amount of lignin and carbohydrates. Its residual lignin was isolated and characterised by P-31-, H-1-NMR and 2D-Homonuclear NMR HOHAHA techniques. These analyses allowed the description of structural details of the ancient wood. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:150 / 154
页数:5
相关论文
共 26 条
[1]  
BABINSKI L, 2001, ROCZ AKAD MED POZN, V340, P53
[2]   High-resolution solid-state CPMAS NMR study of archaeological woods [J].
Bardet, M ;
Foray, MF ;
Trân, QK .
ANALYTICAL CHEMISTRY, 2002, 74 (17) :4386-4390
[3]  
BLANCHETTE RA, 1990, ADV CHEM SER, P141
[4]   Archaeological wood characterisation by PY/GC/MS, GC/MS, NMR and GPC techniques [J].
Colombini, M. P. ;
Orlandi, M. ;
Modugno, F. ;
Tolppa, E. -L. ;
Sardelli, M. ;
Zoia, L. ;
Crestini, C. .
MICROCHEMICAL JOURNAL, 2007, 85 (01) :164-173
[5]   Biomimetic degradation of lignin and lignin model compounds by synthetic anionic and cationic water soluble manganese and iron porphyrins [J].
Crestini, C ;
Saladino, R ;
Tagliatesta, P ;
Boschi, T .
BIOORGANIC & MEDICINAL CHEMISTRY, 1999, 7 (09) :1897-1905
[6]   Structural modifications induced during biodegradation of wheat lignin by Lentinula edodes [J].
Crestini, C ;
Sermanni, GG ;
Argyropoulos, DS .
BIOORGANIC & MEDICINAL CHEMISTRY, 1998, 6 (07) :967-973
[7]   Structural analysis of wheat straw lignin by quantitative P-31 and 2D NMR spectroscopy. The occurrence of ester bonds and alpha-O-4 substructures [J].
Crestini, C ;
Argyropoulos, DS .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1997, 45 (04) :1212-1219
[8]  
CRESTINI C, 1998, 5 EUR WORKSH LIGN PU
[9]  
Dence C.W., 1992, METHODS LIGNIN CHEM, P33, DOI [DOI 10.1007/978-3-642-74065-7_3, 10.1007/978-3-642-74065-7_3]
[10]  
determination, 1988, METHOD ENZYMOL, V161, P87, DOI 10.1016/0076-6879(88161014-7