Catalytic Transfer Hydrogenation/Hydrogenolysis for Reductive Upgrading of Furfural and 5-(Hydroxymethyl)furfural

被引：298

作者：

Scholz, David ^{[1
]}

Aellig, Christof ^{[1
]}

Hermans, Ive ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Inst Chem & Bioengn, CH-8093 Zurich, Switzerland

来源：

CHEMSUSCHEM | 2014年 / 7卷 / 01期

关键词：

biomass; dimethylfuran; furfural; heterogeneous catalysis; hydrogenolysis; TRANSFER HYDROGENOLYSIS; PALLADIUM CATALYSTS; TRANSFER HYDROGENATION; GLYCEROL CONVERSION; BENZYLIC ALCOHOLS; FORMIC-ACID; 2,5-DIMETHYLFURAN; 1,2-PROPANEDIOL; DIMETHYLFURAN; KINETICS;

D O I：

10.1002/cssc.201300774

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sequential transfer hydrogenation/hydrogenolysis of furfural and 5-hydroxymethylfurfural to 2-methylfuran and 2,5-dimethylfuran was studied over in situ reduced, Fe2O3-supported Cu, Ni, and Pd catalysts, with 2-propanol as hydrogen donor. The remarkable activity of Pd/Fe2O3 in both transfer hydrogenation/hydrogenolysis is attributed to a strong metal-support interaction. Selectivity towards hydrogenation, hydrogenolysis, decarbonylation, and ring-hydrogenation products is shown to strongly depend on the Pd loading. A significant enhancement in yield to 62%, of 2-methylfuran and 2-methyltetrahydrofuran was observed under continuous flow conditions.

引用

页码：268 / 275

页数：8

共 41 条

[1] Continuous D-Fructose Dehydration to 5-Hydroxymethylfurfural Under Mild Conditions [J].

Aellig, Christof ;

Hermans, Ive .

CHEMSUSCHEM, 2012, 5 (09) :1737-1742

[2]

[Anonymous], 1995, Handbook of X-ray Photoelectron Spectroscopy. A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data

[3] Synthesis of Furfural from Xylose and Xylan [J].

Binder, Joseph B. ;

Blank, Jacqueline J. ;

Cefali, Anthony V. ;

Raines, Ronald T. .

CHEMSUSCHEM, 2010, 3 (11) :1268-1272

[4] The structure and bonding of furan on Pd(111) [J].

Bradley, M. K. ;

Robinson, J. ;

Woodruff, D. P. .

SURFACE SCIENCE, 2010, 604 (11-12) :920-925

[5] PRODUCTION OF 2-METHYLFURAN BY VAPOR-PHASE HYDROGENATION OF FURFURAL [J].

BURNETTE, LW ;

JOHNS, IB ;

HOLDREN, RF ;

HIXON, RM .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1948, 40 (03) :502-505

[6] Selective hydrogenation of cinnamaldehyde over supported copper catalysts [J].

Chambers, A ;

Jackson, SD ;

Stirling, D ;

Webb, G .

JOURNAL OF CATALYSIS, 1997, 168 (02) :301-314

[7] A two-step approach for the catalytic conversion of glucose to 2,5-dimethylfuran in ionic liquids [J].

Chidambaram, Mandan ;

Bell, Alexis T. .

GREEN CHEMISTRY, 2010, 12 (07) :1253-1262

[8] Catalytic glycerol conversion into 1,2-propanediol in absence of added hydrogen [J].

D'Hondt, Els ;

de Vyver, Stijn Van ;

Sels, Bert F. ;

Jacobs, Pierre A. .

CHEMICAL COMMUNICATIONS, 2008, (45) :6011-6012

[9] CO adsorption on supported Pd catalysts studied by adsorption microcalorimetry and temperature programmed desorption [J].

Dropsch, H ;

Baerns, M .

APPLIED CATALYSIS A-GENERAL, 1997, 158 (1-2) :163-183

[10] Ni/SiO2 and Fe/SiO2 catalysts for production of hydrogen and filamentous carbon via methane decomposition [J].

Ermakova, MA ;

Ermakov, DY .

CATALYSIS TODAY, 2002, 77 (03) :225-235

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