The first N-alkyl-N′-polyfluorohetaryl sulfur diimide

被引：10

作者：

Lork, E

Mews, R ^{[1
]}

Shakirov, MM

Watson, PG

Zibarev, AV

机构：

[1] Univ Bremen, Inst Inorgan & Phys Chem, D-28334 Bremen, Germany

[2] Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 115卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

alkylthiazylamide; fluoroelectrophiles; sulfur diimides; polyfluorinated; X-ray structure determination;

D O I：

10.1016/S0022-1139(02)00047-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first Alk-N=S=N-Het(F) sulfur diimide 6 (Alk = adamant-1-yl, Het(F) = 2,3,5,6-tetrafluoropyrid-4-yl) was prepared by trapping of the corresponding alkylthiazylamide [AlkNSN](-) 3 with pentafluoropyridine, followed by X-ray structural characterization. For 6, the Z,E configuration was found. From the reaction of 3 with octafluoronaphthalene, hexafluorinated naphthothiadiazole 7 was isolated along with the parent AlkNH(2). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：165 / 168

页数：4

共 19 条

[1] CYCLIC ARYLENEAZACHALCOGENENES .8. REGIOSELECTIVITY OF FLUORIDE ION-INDUCED INTRAMOLECULAR NUCLEOPHILIC CYCLIZATION OF HEPTAFLUORONAPHTHYL SULFUR DIIMIDES 2-NF(F)-N=S=N-SIME(3) AND 2-NF(F)S-N=S=N-S1ME(3) [J].