Combined High Stretchability and Gas Barrier in Hydrogen-Bonded Multilayer Nanobrick Wall Thin Films

被引：44
作者：
Qin, Shuang [1 ]
Song, Yixuan [1 ]
Floto, Michael E. [2 ]
Grunlan, Jaime C. [1 ,2 ,3 ]
机构：
[1] Texas A&M Univ, Dept Mat Sci & Engn, College Stn, TX 77843 USA
[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[3] Texas A&M Univ, Dept Mech Engn, College Stn, TX 77843 USA
来源：
ACS APPLIED MATERIALS & INTERFACES | 2017年 / 9卷 / 09期
基金：
美国国家科学基金会;
关键词：
layer-by-layer assembly; hydrogen bonding nanobrick wall structure; oxygen barrier; clay nanoplatelets; EXPONENTIAL-GROWTH; POLYELECTROLYTE; MONTMORILLONITE; OXYGEN; NANOCOMPOSITE; TRANSPARENT; DISPERSION; CLAY;
D O I：
10.1021/acsami.7b00844
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Hydrogen-bonded multilayer thin films are very stretchable, but their gas barrier properties are modest compared to more traditional ionically bonded assemblies. In an effort to improve the gas barrier of poly(ethylene oxide) (PEO) poly(acrylic acid) (PAA) multilayer films without sacrificing stretchability, montmorillonite (MMT) clay platelets were combined with PAA and alternately deposited with PEO. A ten-bilayer PEO/PAA+MMT film (432 nm thick), deposited on a 1 mm PU substrate, resulted in a 54X reduction in oxygen transmission rate after exposure to a 20% strain. This system is the best combination of stretchability and gas barrier ever reported.
引用
收藏
页码：7903 / 7907
页数：5
相关论文
共 31 条
  • [1] Stretchable Thin-Film Electrodes for Flexible Electronics with High Deformability and Stretchability
    Cheng, Tao
    Zhang, Yizhou
    Lai, Wen-Yong
    Huang, Wei
    [J]. ADVANCED MATERIALS, 2015, 27 (22) : 3349 - 3376
  • [2] Combined Ionic and Hydrogen Bonding in Polymer Multi layer Thin Film for High Gas Barrier and Stretchiness
    Cho, Chungyeon
    Xiang, Fangming
    Wallace, Kevin L.
    Grunlan, Jaime C.
    [J]. MACROMOLECULES, 2015, 48 (16) : 5723 - 5729
  • [3] Transparent, Ultrahigh-Gas-Barrier Films with a Brick-Mortar-Sand Structure
    Dou, Yibo
    Pan, Ting
    Xu, Simin
    Yan, Hong
    Han, Jingbin
    Wei, Min
    Evans, David G.
    Duan, Xue
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (33) : 9673 - 9678
  • [4] Viscous Friction of Hydrogen-Bonded Matter
    Erbas, Aykut
    Horinek, Dominik
    Netz, Roland R.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) : 623 - 630
  • [5] Nanoclays reinforced glass ionomer cements: dispersion and interaction of polymer grade (PG) montmorillonite with poly(acrylic acid)
    Fareed, Muhammad A.
    Stamboulis, Artemis
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2014, 25 (01) : 91 - 99
  • [6] Haraguchi K, 2002, ADV MATER, V14, P1120, DOI 10.1002/1521-4095(20020816)14:16<1120::AID-ADMA1120>3.0.CO
  • [7] 2-9
  • [8] Stretchable Gas Barrier Achieved with Partially Hydrogen- Bonded Multilayer Nanocoating
    Holder, Kevin M.
    Spears, Benjamin R.
    Huff, Molly E.
    Priolo, Morgan A.
    Harth, Eva
    Grunlan, Jaime C.
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2014, 35 (10) : 960 - 964
  • [9] Nanomechanical Behavior of High Gas Barrier Multilayer Thin Films
    Humood, Mohammad
    Chowdhury, Shahla
    Song, Yixuan
    Tzeng, Ping
    Grunlan, Jaime C.
    Polycarpou, Andreas A.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (17) : 11128 - 11138
  • [10] Hydrogen-bonded layer-by-layer polymer films
    Kharlampieva, Eugenia
    Sukhishvili, Svetlana A.
    [J]. POLYMER REVIEWS, 2006, 46 (04) : 377 - 395
1234