Recent advances in TiO2-based catalysts for N2 reduction reaction

被引：87

作者：

Chen, Jiayin ^{[1
,2
]}

Zhang, Wei ^{[1
,2
,3
]}

Li, Haoze ^{[1
,2
]}

Li, Wei ^{[1
,2
]}

Zhao, Dongyuan ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Lab Adv Mat, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

[2] Fudan Univ, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China

[3] Zhuhai Fudan Innovat Inst, Hengqin New Distract, Zhuhai, Peoples R China

来源：

SUSMAT | 2021年 / 1卷 / 02期

基金：

中国博士后科学基金; 国家重点研发计划; 中国国家自然科学基金;

关键词：

electrocatalysis; mild conditions; N-2 reduction reaction; photocatalysis; TiO2; ELECTROCATALYTIC N-2-TO-NH3 FIXATION; TITANIUM-DIOXIDE POWDERS; TIO2; 110; SURFACE; AMMONIA-SYNTHESIS; DINITROGEN PHOTOREDUCTION; PHOTOCATALYTIC FIXATION; PHOTOCHEMICAL-SYNTHESIS; AMBIENT-TEMPERATURE; NITROGEN REDUCTION; DOPED TIO2;

D O I：

10.1002/sus2.13

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitrogen (N-2) fixation under mild conditions is a promising approach for green production of ammonia (NH3). In the past decades, various advanced catalysts have been fabricated to achieve this goal through electrocatalytic and photocatalytic processes. Among them, the TiO2-based catalysts have been recognized as promising candidates due to their high activity, low cost, chemical stability, and nontoxicity. In this review, recent advances in the fabrication of high-performance TiO2-based materials for N-2 reduction reaction (NRR) under mild conditions are summarized, including electrocatalytic and photocatalytic NRR. The design principles, synthetic strategies, and corresponding chemical/physical properties of TiO2-based NRR catalysts are described in detail. Moreover, the key challenges and potential opportunities in this field are presented and discussed.

引用

页码：174 / 193

页数：20

共 107 条

[1] Electrochemical Reduction of N2 under Ambient Conditions for Artificial N2 Fixation and Renewable Energy Storage Using N2/NH3 Cycle [J].