High-yield gamma-ray-induced polymerization of bis-2-acetoacetoxyethyl methacrylate copper .2.

被引：0

作者：

Bertolin, M

Zecca, M

Favero, G

Palma, G

Lora, S

Ajo, D

Corain, B

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN METALLORGAN & ANALI,I-35131 PADUA,ITALY

[2] UNIV PADUA,DIPARTIMENTO CHIM FIS,I-35131 PADUA,ITALY

[3] CNR,INST FRAE,I-35020 LEGNARO,ITALY

[4] CNR,ICTIMA,I-35127 PADUA,ITALY

[5] UNIV AQUILA,DIPARTIMENTO CHIM INGN CHIM & MAT,I-67010 LAQUILA,ITALY

[6] CNR,COMPOSTI COORDINAZ,CTR STUDIO STABILITA & REATTIVITA,I-35131 PADUA,ITALY

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1997年 / 65卷 / 11期

关键词：

alpha-acetoacetoxyethyl methacrylate copper(II); gamma-rays; copolymerization; crosslinked copolymers;

D O I：

10.1002/(SICI)1097-4628(19970912)65:11<2201::AID-APP17>3.0.CO;2-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The copper (II) acrylic monomer Cu(aaem)(2) (aaem = 2-acetoacetoxyethyl methacrylate) undergoes high-yield gamma-ray copolymerization with dimethylacrylamide, styrene, and hydroxoethyl methacrylate in the presence of methylene bisacrylamide as crosslinking agent in dimethylformamide. The metalloorganic copolymers are fully characterized. Polymer-protected Cu(II) results in being extremely stable toward a number of reducing agents in different media. (C) 1997 John Wiley & Sons, Inc.

引用

页码：2201 / 2207

页数：7