High-yield gamma-ray-induced polymerization of bis-2-acetoacetoxyethyl methacrylate copper .2.

被引：0
|
作者：
Bertolin, M
Zecca, M
Favero, G
Palma, G
Lora, S
Ajo, D
Corain, B
机构：
[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN METALLORGAN & ANALI,I-35131 PADUA,ITALY
[2] UNIV PADUA,DIPARTIMENTO CHIM FIS,I-35131 PADUA,ITALY
[3] CNR,INST FRAE,I-35020 LEGNARO,ITALY
[4] CNR,ICTIMA,I-35127 PADUA,ITALY
[5] UNIV AQUILA,DIPARTIMENTO CHIM INGN CHIM & MAT,I-67010 LAQUILA,ITALY
[6] CNR,COMPOSTI COORDINAZ,CTR STUDIO STABILITA & REATTIVITA,I-35131 PADUA,ITALY
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 1997年 / 65卷 / 11期
关键词：
alpha-acetoacetoxyethyl methacrylate copper(II); gamma-rays; copolymerization; crosslinked copolymers;
D O I：
10.1002/(SICI)1097-4628(19970912)65:11<2201::AID-APP17>3.0.CO;2-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The copper (II) acrylic monomer Cu(aaem)(2) (aaem = 2-acetoacetoxyethyl methacrylate) undergoes high-yield gamma-ray copolymerization with dimethylacrylamide, styrene, and hydroxoethyl methacrylate in the presence of methylene bisacrylamide as crosslinking agent in dimethylformamide. The metalloorganic copolymers are fully characterized. Polymer-protected Cu(II) results in being extremely stable toward a number of reducing agents in different media. (C) 1997 John Wiley & Sons, Inc.
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页码：2201 / 2207
页数：7
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