Improvement of photo-stability of LLDPE-based nanocomposites

被引：51
|
作者：
La Mantia, F. P.
Dintcheva, N. Tzankova
Malatesta, V.
Pagani, F.
机构：
[1] Cytec Ind Italy, I-20121 Milan, Italy
[2] Univ Palermo, Dipartimento Ingn Chim Proc & Mat, I-90128 Palermo, Italy
来源：
POLYMER DEGRADATION AND STABILITY | 2006年 / 91卷 / 12期
关键词：
photo-oxidation; photo-stability; LLDPE-based nanocomposites; metal deactivator; mechanical properties;
D O I：
10.1016/j.polymdegradstab.2006.07.014
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
LLDPE-based nanocomposites undergo faster photo-oxidation than the unfilled matrix and the extent of their physical properties deterioration, namely elongation at break and tensile strength, is dependent on the organo-nanoclay loading. The observed acceleration is not due to faster photo-oxidation but rather due to a reduction of the oxidation induction time. The presence in the organoclays of trace amounts of metal ions may be promoting catalytic photodegradation. While UV absorbers provide useful protection, use of a metal deactivator has been found to greatly enhance the photo-stability of the LLDPE-based nanocomposites. Combinations of a metal deactivator and UV absorber yield synergistic effects. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3208 / 3213
页数：6
相关论文
共 50 条
  • [1] On photo-stability of oxybenzone
    Santoro, E
    JOURNAL OF INVESTIGATIVE DERMATOLOGY, 1998, 110 (01) : 95 - 96
  • [2] A Comparison of LLDPE-based Nanocomposites Containing Multi-walled Carbon Nanotubes and Graphene
    Vasileiou, Alexandros
    Docoslis, Aristides
    Kontopoulou, Marianna
    PROCEEDINGS OF PPS-30: THE 30TH INTERNATIONAL CONFERENCE OF THE POLYMER PROCESSING SOCIETY, 2015, 1664
  • [3] Enhanced photo-stability of conjugated polymer nanocomposites doped with functionalized nanoparticles
    Lim, YT
    Lee, TW
    Lee, HC
    Park, OO
    OPTICAL MATERIALS, 2003, 21 (1-3) : 585 - 589
  • [4] Effect of LDPE on the thermomechanical properties of LLDPE-based films
    Niaounakis, M
    Kontou, E
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2005, 43 (13) : 1712 - 1727
  • [5] On photo-stability of oxybenzone - Reply
    Schallreuter, KU
    Moore, J
    Wood, JM
    JOURNAL OF INVESTIGATIVE DERMATOLOGY, 1998, 110 (01) : 96 - 97
  • [6] Influence of polymer morphology on photo-stability of polypropylene/SiO2 nanocomposites
    Sumino, Ken-ichi
    Asuka, Kazuo
    Liu, Boping
    Yamaguchi, Masayuki
    Terano, Minoru
    Kawamura, Takanobu
    Nitta, Koh-hei
    PROGRESS IN OLEFIN POLYMERIZATION CATALYSTS AND POLYOLEFIN MATERIALS, PROCEEDINGS OF THE FIRST ASIAN POLYOLEFIN WORKSHOP, 2006, 161 : 229 - 232
  • [7] Improvement of the photo-stability of polystyrene-block-polybutadiene-block-polystyrene through carbon nanotubes
    Dintcheva, Nadka Tzankova
    Arrigo, Rossella
    Catalanotto, Francesco
    Morici, Elisabetta
    POLYMER DEGRADATION AND STABILITY, 2015, 118 : 24 - 32
  • [8] Surfactant Enhancing Photo-Stability of Folic Acid
    Liu Minghua
    ACTA PHYSICO-CHIMICA SINICA, 2019, 35 (07) : 663 - 664
  • [9] PHOTO-STABILITY OF SEVERAL CRYSTAL FORMS OF CIANIDANOL
    AKIMOTO, K
    INOUE, K
    SUGIMOTO, I
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1985, 33 (09) : 4050 - 4053
  • [10] Photo-stability of coloring constituents in paprika color
    Goda, Y
    Nakamura, H
    Sakamoto, SS
    Ishikawa, K
    Maitani, T
    Yamada, T
    JOURNAL OF THE FOOD HYGIENIC SOCIETY OF JAPAN, 1997, 38 (04): : 240 - 247
12345