Heterogeneously Catalysed Hydroamination

被引：25

作者：

Sengupta, Manideepa ^{[1
,2
]}

Das, Subhasis ^{[3
]}

Islam, Sk. Manirul ^{[2
]}

Bordoloi, Ankur ^{[1
,4
]}

机构：

[1] Indian Inst Petr, CSIR, Nano Catalysis Light Stock Proc Div, Dehra Dun 248005, Uttar Pradesh, India

[2] Univ Kalyani, Dept Chem, Kalyani 741235, W Bengal, India

[3] Ruhr Univ Bochum, Lab Ind Chem, D-44780 Bochum, Germany

[4] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India

来源：

CHEMCATCHEM | 2021年 / 13卷 / 04期

关键词：

Hydroamination; organo-nitrogen compounds; heterogeneous catalysis; INTERMOLECULAR HYDROAMINATION; INTRAMOLECULAR HYDROAMINATION; EXCHANGED MONTMORILLONITE; TUNGSTOPHOSPHORIC ACID; ALKYNE HYDROAMINATION; TERMINAL ALKYNES; DIRECT ADDITION; IONIC LIQUID; EFFICIENT; AMINATION;

D O I：

10.1002/cctc.202001394

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The direct addition of amines to alkynes and olefins is an elegant approach for C-N bond formation in contrast to other conventional synthetic organic methods that afford higher substituted amines; comprising essential organo-nitrogen compounds which are the scaffolds present in important N-heterocycles. Heterogeneous catalyzed direct amination is presented in this Review, along with the advantages, the structure-activity relationship of applied solid acids, functionalized nanomaterials and heterogeneous single metal site catalysts that play a pivotal role towards tuning the formation of branched and linear amines.

引用

页码：1089 / 1104

页数：16

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