Upscaling Inverted Perovskite Solar Cells: Optimization of Laser Scribing for Highly Efficient Mini-Modules

被引:50
作者
Di Giacomo, Francesco [1 ]
Castriotta, Luigi A. [1 ]
Kosasih, Felix U. [2 ]
Di Girolamo, Diego [3 ]
Ducati, Caterina [2 ]
Di Carlo, Aldo [1 ,4 ]
机构
[1] Univ Roma Tor Vergata, Ctr Hybrid & Organ Solar Energy CHOSE, Dept Elect Engn, I-00133 Rome, Italy
[2] Univ Cambridge, Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, England
[3] Univ Naples Federico II, Dept Chem Mat & Prod Engn, Piazzale Tecchio 80, I-80125 Naples, Italy
[4] Natl Univ Sci & Technol MISiS, LASE Lab Adv Solar Energy, Leninsky Ave 6, Moscow 119049, Russia
基金
欧盟地平线“2020”;
关键词
perovskite solar cells; laser ablation; perovskite solar module;
D O I
10.3390/mi11121127
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The upscaling of perovskite solar cells is one of the challenges that must be addressed to pave the way toward the commercial development of this technology. As for other thin-film photovoltaic technologies, upscaling requires the fabrication of modules composed of series-connected cells. In this work we demonstrate for the first time the interconnection of inverted modules with NiOx using a UV ns laser, obtaining a 10.2 cm(2) minimodule with a 15.9% efficiency on the active area, the highest for a NiOx based perovskite module. We use optical microscopy, energy-dispersive X-ray spectroscopy, and transfer length measurement to optimize the interconnection. The results are implemented in a complete electrical simulation of the cell-to-module losses to evaluate the experimental results and to provide an outlook on further development of single junction and multijunction perovskite modules.
引用
收藏
页码:1 / 13
页数:13
相关论文
共 33 条
[1]   Electron-Beam-Evaporated Nickel Oxide Hole Transport Layers for Perovskite-Based Photovoltaics [J].
Abzieher, Tobias ;
Moghadamzadeh, Somayeh ;
Schackmar, Fabian ;
Eggers, Helge ;
Sutterlueti, Florian ;
Farooq, Amjad ;
Kojda, Danny ;
Habicht, Klaus ;
Schmager, Raphael ;
Mertens, Adrian ;
Azmi, Raheleh ;
Klohr, Lukas ;
Schwenzer, Jonas A. ;
Hetterich, Michael ;
Lemmer, Uli ;
Richards, Bryce S. ;
Powalla, Michael ;
Paetzold, Ulrich W. .
ADVANCED ENERGY MATERIALS, 2019, 9 (12)
[2]   Planar perovskite solar cells with long-term stability using ionic liquid additives [J].
Bai, Sai ;
Da, Peimei ;
Li, Cheng ;
Wang, Zhiping ;
Yuan, Zhongcheng ;
Fu, Fan ;
Kawecki, Maciej ;
Liu, Xianjie ;
Sakai, Nobuya ;
Wang, Jacob Tse-Wei ;
Huettner, Sven ;
Buecheler, Stephan ;
Fahlman, Mats ;
Gao, Feng ;
Snaith, Henry J. .
NATURE, 2019, 571 (7764) :245-+
[3]   Reduced Self-Doping of Perovskites Induced by Short Annealing for Efficient Solar Modules [J].
Deng, Yehao ;
Ni, Zhenyi ;
Palmstrom, Axel F. ;
Zhao, Jingjing ;
Xu, Shuang ;
Van Brackle, Charles H. ;
Xiao, Xun ;
Zhu, Kai ;
Huang, Jinsong .
JOULE, 2020, 4 (09) :1949-1960
[4]   Progress, highlights and perspectives on NiO in perovskite photovoltaics [J].
Di Girolamo, Diego ;
Di Giacomo, Francesco ;
Matteocci, Fabio ;
Marrani, Andrea Giacomo ;
Dini, Danilo ;
Abate, Antonio .
CHEMICAL SCIENCE, 2020, 11 (30) :7746-7759
[5]   Ion Migration-Induced Amorphization and Phase Segregation as a Degradation Mechanism in Planar Perovskite Solar Cells [J].
Di Girolamo, Diego ;
Nga Phung ;
Kosasih, Felix Utama ;
Di Giacomo, Francesco ;
Matteocci, Fabio ;
Smith, Joel A. ;
Flatken, Marion A. ;
Koebler, Hans ;
Cruz, Silver H. Turren ;
Mattoni, Alessandro ;
Cina, Lucio ;
Rech, Bernd ;
Latini, Alessandro ;
Divitini, Giorgio ;
Ducati, Caterina ;
Di Carlo, Aldo ;
Dini, Danilo ;
Abate, Antonio .
ADVANCED ENERGY MATERIALS, 2020, 10 (25)
[6]   From Bulk to Surface: Sodium Treatment Reduces Recombination at the Nickel Oxide/Perovskite Interface [J].
Di Girolamo, Diego ;
Phung, Nga ;
Jost, Marko ;
Al-Ashouri, Amran ;
Chistiakova, Ganna ;
Li, Junming ;
Marquez, Jose A. ;
Unold, Thomas ;
Korte, Lars ;
Albrecht, Steve ;
Di Carlo, Aldo ;
Dini, Danilo ;
Abate, Antonio .
ADVANCED MATERIALS INTERFACES, 2019, 6 (17)
[7]   Towards the scaling up of perovskite solar cells and modules [J].
Galagan, Y. ;
Coenen, E. W. C. ;
Verhees, W. J. H. ;
Andriessen, Ronn .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (15) :5700-5705
[8]   CIGS thin-film solar module processing: case of high-speed laser scribing [J].
Gecys, Paulius ;
Markauskas, Edgaras ;
Nishiwaki, Shiro ;
Buecheler, Stephan ;
De Loor, Ronny ;
Burn, Andreas ;
Romano, Valerio ;
Raciukaitis, Gediminas .
SCIENTIFIC REPORTS, 2017, 7
[9]   Transparent conducting oxides [J].
Ginley, DS ;
Bright, C .
MRS BULLETIN, 2000, 25 (08) :15-18
[10]   Series-Connection Designs for Dye Solar Cell Modules [J].
Giordano, Fabrizio ;
Petrolati, Eleonora ;
Brown, Thomas M. ;
Reale, Andrea ;
Di Carlo, Aldo .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2011, 58 (08) :2759-2764