Relativistic configuration-interaction calculations for atoms with one valence electron based on altering hydrogenlike or Dirac-Fock spin orbitals

被引:3
作者
Glowacki, Leszek [1 ]
机构
[1] Pedag Univ Cracow, Dept Comp Sci & Comp Methods, PL-30084 Krakow, Poland
来源
PHYSICAL REVIEW A | 2015年 / 92卷 / 06期
关键词
OSCILLATOR-STRENGTHS; CORE POLARIZATION; TRANSITIONS;
D O I
10.1103/PhysRevA.92.062505
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Relativistic configuration-interaction calculations using hydrogenlike or Dirac-Fock spin orbitals of the transition from the ground state to some np(1/2), np(3/2) low-lying excited states for the alkali metals are presented. In these calculations each virtual spin orbital corresponds to a unique noninteger atomic number determined iteratively using the virtual-particle model. The virtual-particle model based on "condensed-space" idea is here adopted to many electron systems consisting of a single valence electron and the core. The transition energy and the oscillator strength values were computed for sodium, potassium, rubidium, cesium, and francium. Both hydrogenlike and Dirac-Fock basis functions have been used in the computations for comparison.
引用
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页数:8
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