Metal-organic frameworks as heterogeneous photocatalysts: advantages and challenges

被引：426

作者：

Nasalevich, M. A. ^{[1
]}

van der Veen, M. ^{[1
]}

Kapteijn, F. ^{[1
]}

Gascon, J. ^{[1
]}

机构：

[1] Delft Univ Technol, Dept Chem Engn, NL-2628 BL Delft, Netherlands

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 23期

关键词：

VISIBLE-LIGHT; PHOSPHOTUNGSTIC ACID; HYDROGEN-PRODUCTION; ENERGY-TRANSFER; WATER; OXIDATION; REDUCTION; MOFS; BEHAVIOR; TIO2;

D O I：

10.1039/c4ce00032c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of metal organic frameworks (MOFs) as heterogeneous photocatalysts is critically reviewed. First we revisit the general assumption of MOFs behaving truly as semiconductors, demonstrating that such semiconducting behaviour only occurs in a very limited subset of materials. Further, the main approaches for efficient light harvesting and active site engineering in MOF-based photocatalysts are discussed. Finally, the main advantages of MOFs as photocatalysts and the challenges that need to be addressed in order to improve catalytic performance are evaluated.

引用

页码：4919 / 4926

页数：8

共 84 条

[61] Charge carrier dynamics in TiO2 nanoparticles at various temperatures [J].

Savenije, Tom J. ;

Huijser, Annemarie ;

Vermeulen, Martien J. W. ;

Katoh, Ryuzi .

CHEMICAL PHYSICS LETTERS, 2008, 461 (1-3) :93-96

[62] Revealing the Dynamics of Charge Carriers in Polymer:Fullerene Blends Using Photoinduced Time-Resolved Microwave Conductivity [J].

Savenije, Tom J. ;

Ferguson, Andrew J. ;

Kopidakis, Nikos ;

Rumbles, Garry .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (46) :24085-24103

[63]

Schiavello Mario., 1997, Heterogeneous Photocatalysis

[64]

Scholes GD, 2011, NAT CHEM, V3, P763, DOI [10.1038/nchem.1145, 10.1038/NCHEM.1145]

[65] A homochiral metal-organic porous material for enantioselective separation and catalysis [J].

Seo, JS ;

Whang, D ;

Lee, H ;

Jun, SI ;

Oh, J ;

Jeon, YJ ;

Kim, K .

NATURE, 2000, 404 (6781) :982-986

[66] Water Stable Zr-Benzenedicarboxylate Metal-Organic Frameworks as Photocatalysts for Hydrogen Generation [J].

Silva, Claudia Gomes ;

Luz, Ignacio ;

Llabres i Xamena, Francesc X. ;

Corma, Avelino ;

Garcia, Hermenegildo .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (36) :11133-11138

[67] Carbon Dioxide Capture in Metal-Organic Frameworks [J].

Sumida, Kenji ;

Rogow, David L. ;

Mason, Jarad A. ;

McDonald, Thomas M. ;

Bloch, Eric D. ;

Herm, Zoey R. ;

Bae, Tae-Hyun ;

Long, Jeffrey R. .

CHEMICAL REVIEWS, 2012, 112 (02) :724-781

[68] Studies on Photocatalytic CO2 Reduction over NH2-Uio-66(Zr) and Its Derivatives: Towards a Better Understanding of Photocatalysis on Metal-Organic Frameworks [J].

Sun, Dengrong ;

Fu, Yanghe ;

Liu, Wenjun ;

Ye, Lin ;

Wang, Dengke ;

Yang, Lin ;

Fu, Xianzhi ;

Li, Zhaohui .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (42) :14279-14285

[69] Mn2(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal-Organic Framework with Infinite (-Mn-S-)∞ Chains and High Intrinsic Charge Mobility [J].

Sun, Lei ;

Miyakai, Tomoyo ;

Seki, Shu ;

Dinca, Mircea .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (22) :8185-8188

[70] Post-synthetic cation exchange in the robust metal-organic framework MIL-101(Cr) [J].

Szilagyi, Petra A. ;

Serra-Crespo, Pablo ;

Dugulan, Iulian ;

Gascon, Jorge ;

Geerlings, Hans ;

Dam, Bernard .

CRYSTENGCOMM, 2013, 15 (47) :10175-10178

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