共 164 条
Methane conversion into different hydrocarbons or oxygenates: current status and future perspectives in catalyst development and reactor operation
被引:215
作者:

Kondratenko, Evgenii V.
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Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany

Peppel, Tim
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Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany

Seeburg, Dominik
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Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany

Kondratenko, Vita A.
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Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany

Kalevaru, Narayana
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Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany

Martin, Andreas
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机构:
Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany

Wohlrab, Sebastian
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Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany
机构:
[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany
关键词:
BED CHROMATOGRAPHIC REACTOR;
CHELATING BIS(NHC) LIGANDS;
ARTIFICIAL NEURAL-NETWORK;
LOW-TEMPERATURE OXIDATION;
SELECTIVE OXIDATION;
HYDROGEN-PEROXIDE;
BIOLOGICAL CONVERSION;
EFFICIENT CONVERSION;
CH FUNCTIONALIZATION;
MECHANISTIC INSIGHTS;
D O I:
10.1039/c6cy01879c
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
This Perspective highlights recent developments in methane conversion into different hydrocarbons and oxygenates (methanol, its derivatives, and formaldehyde) with the purpose to address the global demand for efficient and environmentally friendly production of these bulk chemicals. Our analysis identified possible directions for further research to bring the above approaches to a commercial level. As no progress in the development of catalysts for the oxidative coupling of methane could be identified, improvements are expected through reactor operation, cost- and energy-efficient methods for product separation and for providing pure oxygen. With respect to methane oxidation to methanol, further progress can also be achieved by proper catalyst design on the basis of fundamental knowledge especially gained from homogeneous and enzymatic catalysts as well as from theoretical calculations.
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页码:366 / 381
页数:16
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