Hierarchically porous nitrogen-rich carbon derived from wheat straw as an ultra-high-rate anode for lithium ion batteries

被引:229
作者
Chen, Li [1 ]
Zhang, Yongzhi [2 ]
Lin, Chaohong [3 ]
Yang, Wen [3 ]
Meng, Yan [3 ]
Guo, Yong [1 ]
Li, Menglong [1 ]
Xiao, Dan [1 ,2 ]
机构
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
[2] Sichuan Univ, Inst New Energy & Low Carbon Technol, Chengdu 610065, Peoples R China
[3] Sichuan Univ, Coll Chem Engn, Chengdu 610065, Peoples R China
关键词
CAPACITIVE ENERGY-STORAGE; HYDROTHERMAL CARBONIZATION; LIGNOCELLULOSIC BIOMASS; GRAPHENE NANOSHEETS; MESOPOROUS CARBON; RATE CAPABILITY; PERFORMANCE; SUPERCAPACITORS; INSERTION; GRAPHITE;
D O I
10.1039/c4ta00501e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A facile, economical and effective method to produce hierarchically porous nitrogen-rich carbon (HPNC) from wheat straw has been reported. Acid pretreatment is introduced before KOH activation, and plays the role of promoting the formation of thinner pore walls. Without any N-doping, the N content is as high as 5.13%. The HPNC when used as an anode for Li-ion batteries exhibits a superior specific capacity of 1470 mA h g(-1) at 0.037 A g(-1), and possesses an ultrahigh rate capability of 344 mA h g(-1) at 18.5 A g(-1). Even at an extremely high current density of 37 A g(-1), the reversible capacity is still as high as 198 mA h g(-1).
引用
收藏
页码:9684 / 9690
页数:7
相关论文
共 49 条
[41]  
Winter M, 1998, ADV MATER, V10, P725, DOI 10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO
[42]  
2-Z
[43]   Graphite and carbon powders for electrochemical applications [J].
Wissler, M .
JOURNAL OF POWER SOURCES, 2006, 156 (02) :142-150
[44]   Preparation and Li Storage Properties of Hierarchical Porous Carbon Fibers Derived from Alginic Acid [J].
Wu, Xing-Long ;
Chen, Li-Li ;
Xin, Sen ;
Yin, Ya-Xia ;
Guo, Yu-Guo ;
Kong, Qing-Shan ;
Xia, Yan-Zhi .
CHEMSUSCHEM, 2010, 3 (06) :703-707
[45]   Effects of nitrogen on the carbon anode of a lithium secondary battery [J].
Wu, YP ;
Fang, SB ;
Jiang, YY .
SOLID STATE IONICS, 1999, 120 (1-4) :117-123
[46]   Doped Graphene Sheets As Anode Materials with Superhigh Rate and Large Capacity for Lithium Ion Batteries [J].
Wu, Zhong-Shuai ;
Ren, Wencai ;
Xu, Li ;
Li, Feng ;
Cheng, Hui-Ming .
ACS NANO, 2011, 5 (07) :5463-5471
[47]   Nanographene-Constructed Hollow Carbon Spheres and Their Favorable Electroactivity with Respect to Lithium Storage [J].
Yang, Shubin ;
Feng, Xinliang ;
Zhi, Linjie ;
Cao, Qian ;
Maier, Joachim ;
Muellen, Klaus .
ADVANCED MATERIALS, 2010, 22 (07) :838-+
[48]   Silicon nanowires for Li-based battery anodes: a review [J].
Zamfir, Mihai Robert ;
Hung Tran Nguyen ;
Moyen, Eric ;
Lee, Young Hee ;
Pribat, Didier .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (34) :9566-9586
[49]   Hierarchical porous carbon derived from rice straw for lithium ion batteries with high-rate performance [J].
Zhang, Feng ;
Wang, Kai-Xue ;
Li, Guo-Dong ;
Chen, Jie-Sheng .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (01) :130-133