An electrocatalytic three-component reaction for the synthesis of phosphoroselenoates

被引：9

作者：

Zhang, Chi ^{[2
,3
]}

Zhou, Yaqin ^{[1
]}

Zhao, Zhiheng ^{[1
]}

Xue, Wei ^{[1
]}

Gu, Lijun ^{[1
]}

机构：

[1] Guizhou Univ, Key Lab Green Pesticide & Agr Bioengn, Minist Educ, Guiyang 550025, Peoples R China

[2] Yunnan Minzu Univ, Key Lab Chem Ethn Med Resources, State Ethn Affairs Commiss, Kunming 650500, Yunnan, Peoples R China

[3] Yunnan Minzu Univ, Minist Educ, Kunming 650500, Yunnan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 100期

基金：

中国国家自然科学基金;

关键词：

SP(3) C-H; OXIDES; METAL; ELECTROSYNTHESIS; PHOSPHONATES; ALKENES; SULFUR; BOND;

D O I：

10.1039/d2cc05570h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphoroselenoates are important organic molecules because they have found widespread applications in many fields. Herein, an efficient electrochemical dehydrogenative approach to prepare phosphoroselenoates from (hetero)arenes and phosphonates using elemental selenium as the selenium source is reported. This approach is compatible with various functional groups and can be easily scaled up. Our control experiments revealed that electricity plays an important role in this transformation.

引用

页码：13951 / 13954

页数：4

共 48 条

[41] Nickel-catalyzed decarboxylative cross-coupling of indole-3-acetic acids with aryl bromides by convergent paired electrolysis [J].