A highly sensitive and selective fluorescent sensor for Al3+ and Zn2+ based on diarylethene with an aminouracil unit

被引:16
作者
Lu, Ruimin [1 ]
Cui, Shiqiang [1 ]
Li, Shuying [1 ]
Pu, Shouzhi [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Diarylethene; Fluorescent sensor; 5-aminouracil unit; Multi-responsive; Logic circuit; PHOTOCHROMIC DIARYLETHENE; ALUMINUM TOXICITY; METAL-COMPLEXES; ZINC; PROBE; RECOGNITION; MECHANISM; CU2+; CELL; ION;
D O I
10.1016/j.tet.2016.12.078
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel diarylethene containing a 5-aminouracil unit was synthesized. Its multi-responsive properties induced by base/acid, UV/Vis lights, and metal ions were investigated in detail. The diarylethene was highly selective towards Al3+ and Zn2+ with obvious fluorescence changes and different binding modes. Furthermore, based on the multi-addressable characteristics, two logic circuits were constructed by using both IJV/Vis lights and chemical species stimuli as inputs and fluorescence intensity as outputs. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:915 / 922
页数:8
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