Ion Association Trends in Alkaline Earth-Metal Tetraphenylborates

被引：13

作者：

Verma, Abhilasha ^{[1
]}

Guino-o, Marites ^{[1
]}

Gillett-Kunnath, Miriam ^{[1
]}

Teng, Weijie ^{[1
]}

Ruhlandt-Senge, Karin ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Ctr Sci & Technol 1 014, Syracuse, NY 13244 USA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 6-7期

基金：

美国国家科学基金会;

关键词：

Alkaline earth metals; Tetraphenylborate; Ion association; Weakly coordinating anion; RING-OPENING POLYMERIZATION; STRUCTURAL-CHARACTERIZATION; LANTHANIDE COMPLEXES; CRYSTAL-STRUCTURES; CALCIUM INITIATORS; ARYL-CALCIUM; SOLID-STATE; BARIUM; COORDINATION; REACTIVITY;

D O I：

10.1002/zaac.200900081

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A family of cationic heavy alkaline earth-metal complexes based oil the weakly coordinating tetraphenylborate anion [BPh4](-) provides unique insight into ion association trends within this family of compounds. The compounds were prepared by protonolysis of the respective alkaline earth-metal bis[bis(trimethylsilyl)]amides M[N(SiMe3)(2)](2)(thf)(2) (M = Ca, Sr, Ba) with ammonium tetraphenylborates [R3NH][BPh4] (R = Me, Et) in various stoichiometric ratios, resulting in the separated ions [M(donor)(n)][BPh4](2) (M = Ca, Sr, Ba; n = number of donors). All compounds but [Ba(hmpa)(6)][BPh4](2) (3c) were characterized using single-crystal Xray diffraction, H-1 and C-13 NMR, IR spectroscopy and melting point.

引用

页码：903 / 913

页数：11

共 110 条

[1] Alkali metal diphenylmethanides: Synthetic, computational and structural studies [J].

Alexander, Jacob S. ;

Allis, Damian G. ;

Teng, Weijie ;

Ruhlandt-Senge, Karin .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (35) :9899-9911

[2] More arrows in the quiver: New pathways and old problems with heavy alkaline earth metal diphenylmethanides [J].

Alexander, JS ;

Ruhlandt-Senge, K .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (05) :1274-1280

[3] An examination of metal-ligand binding modes in rubidium diphenylmethanide [J].

Alexander, JS ;

Allis, DG ;

Hudson, BS ;

Ruhlandt-Senge, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (49) :15002-15003

[4] Synthesis and preparation of alkaline-earth-metal triphenylmethanides M(CPh3)2(18-crown-6)(HMPA)2 and the ether scission products [M(C12H23O6) (N(SiMe3)2)]2 (M = Sr, Ba) [J].

Alexander, JS ;

Ruhlandt-Senge, K ;

Hope, H .

ORGANOMETALLICS, 2003, 22 (24) :4933-4937

[5]

Alexander JS, 2001, ANGEW CHEM INT EDIT, V40, P2658, DOI 10.1002/1521-3773(20010716)40:14<2658::AID-ANIE2658>3.0.CO

[6]

2-Y

[7] 1-SILA-3-METALLACYCLOBUTANES, PRECURSORS FOR THE GENERATION OF HIGHLY ELECTROPHILIC GROUP-4 METALLOCENE ALKYL CATIONS - SPECTROSCOPIC AND STRUCTURAL EVIDENCE OF A WEAKLY BOUND THF LIGAND IN [(C5ME5)2ZR(CH2SIME3)(THF)][BPH4] [J].

AMOROSE, DM ;

LEE, RA ;

PETERSEN, JL .

ORGANOMETALLICS, 1991, 10 (07) :2191-2198

[8] COMPLEXES OF THE PODAND LIGAND TRIS[3-(2-PYRIDYL)-PYRAZOL-1-YL]BORATE WITH LANTHANOIDS AND ACTINOIDS - RARE EXAMPLES OF ICOSAHEDRAL N-12 COORDINATION [J].

AMOROSO, AJ ;

JEFFERY, JC ;

JONES, PL ;

MCCLEVERTY, JA ;

REES, L ;

RHEINGOLD, AL ;

SUN, YM ;

TAKATS, J ;

TROFIMENKO, S ;

WARD, MD ;

YAP, GPA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (18) :1881-1882

[9] CRYSTAL-CHEMISTRY OF TETRARADIAL SPECIES .4. HYDROGEN-BONDING TO AROMATIC PI-SYSTEMS - CRYSTAL-STRUCTURES OF 15 TETRAPHENYLBORATES WITH ORGANIC AMMONIUM CATIONS [J].

BAKSHI, PK ;

LINDEN, A ;

VINCENT, BR ;

ROE, SP ;

ADHIKESAVALU, D ;

CAMERON, TS ;

KNOP, O .

CANADIAN JOURNAL OF CHEMISTRY, 1994, 72 (05) :1273-1293

[10] One ligand fits all: Cationic mono(amidinate) alkyl catalysts over the full size range of the group 3 and lanthanide metals [J].

Bambirra, S ;

Bouwkamp, MW ;

Meetsma, A ;

Hessen, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (30) :9182-9183

← 1 2 3 4 5 6 7 8 9 10 →