Radical polymerization of 'dehydroaspirin' with the formation of a hemiacetal ester skeleton: a hint for recyclable vinyl polymers

被引：37
作者：
Kazama, Akane [1 ]
Kohsaka, Yasuhiro [1 ,2 ]
机构：
[1] Shinshu Univ, Fac Text Sci & Technol, 3-15-1 Tokida, Ueda, Nagano 3868567, Japan
[2] Shinshu Univ, RISM, Ueda, Nagano, Japan
来源：
POLYMER CHEMISTRY | 2019年 / 10卷 / 22期
关键词：
LIVING CATIONIC-POLYMERIZATION; POLYETHYLENE TEREPHTHALATE; SUSTAINABLE POLYMERS; SIDE-CHAIN; ACID; POLYPEROXIDES; TEMPERATURE; COPOLYMERS; POLYESTER; KINETICS;
D O I：
10.1039/c9py00474b
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A vinyl polymer with a cyclic hemiacetal ester skeleton was synthesized via the radical polymerization of 2-methylene-4H-benzo [d][1,3] dioxin-4-one (MBDO; so-called ` dehydroaspirin'). This material could be decomposed to acetic acid and salicylic acid (the raw ingredients for MBDO) by acid hydrolysis, and thus has potential as a recyclable vinyl polymer.
引用
收藏
页码：2764 / 2768
页数：5
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