Design Strategies for Vanadium-based Aqueous Zinc-Ion Batteries

被引:768
作者
Wan, Fang [1 ]
Niu, Zhiqiang [1 ]
机构
[1] Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
aqueous ZIBs; cathodes; electrolytes; energy storage mechanisms; vanadium-based compounds; CATHODE MATERIAL; PERFORMANCE; LI; CHEMISTRY;
D O I
10.1002/anie.201903941
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aqueous zinc-ion batteries (ZIBs) are considered promising energy storage devices for large-scale energy storage systems as a consequence of their safety benefits and low cost. In recent years, various vanadium-based compounds have been widely developed to serve as the cathodes of aqueous ZIBs because of their low cost and high theoretical capacity. Furthermore, different energy storage mechanisms are observed in ZIBs based on vanadium-based cathodes. In this Minireview, we present a comprehensive overview of the energy storage mechanisms and structural features of various vanadium-based cathodes in ZIBs. Furthermore, we discuss strategies for improving the electrochemical performance of vanadium-based cathodes; including, insertion of metal ions, adjustment of structural water, selection of conductive additives, and optimization of electrolytes. Finally, this Minireview offers insight into potential future directions in the design of innovative vanadium-based electrode materials.
引用
收藏
页码:16358 / 16367
页数:10
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