Synthesis of N-Sulfonylamidines by Catalyst-Free Hydroamination of Ynamides and Amines

被引：18

作者：

Kong, Yulong ^{[1
]}

Yu, Lian ^{[1
]}

Cui, Yuming ^{[1
]}

Cao, Jian ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2014年 / 46卷 / 02期

基金：

中国国家自然科学基金;

关键词：

amines; sulfonamides; aminations; ONE-POT SYNTHESIS; SUBSTITUTED YNAMIDES; INTERMOLECULAR HYDROAMINATION; ELECTROPHILIC CYCLIZATION; OXIDATIVE ALKYNYLATION; EFFICIENT SYNTHESIS; TERMINAL ALKYNES; GOLD(I) COMPLEX; BOND FORMATION; AMIDATION;

D O I：

10.1055/s-0033-1340287

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel synthesis of N-sulfonylamidines by catalyst-free hydroamination of N, N-disulfonyl ynamides with amines was developed. Alkyl amines react with N, N-disulfonyl ynamides under mild conditions, whereas aryl amines require higher temperatures. Plausible mechanisms are proposed to explain this reaction.

引用

页码：183 / 188

页数：6

共 50 条

[41] Catalyst-Free Transamidation of Aromatic Amines with Formamide Derivatives and Tertiary Amides with Aliphatic Amines
Yin, Jiawen
Zhang, Jingyu
Cai, Changqun
Deng, Guo-Jun
Gong, Hang
ORGANIC LETTERS, 2019, 21 (02) : 387 - 392
[42] One-pot synthesis of N-sulfonylamidines from N-acylsulfonamides enabled by a metal triflate-mediated nonhydrolytic N-deacylation
Tian, Juan
Chen, Mengyun
Wang, Xinyi
Chen, Xin
Shao, Chengya
Xiong, Yiting
Liu, Yunfeng
Sang, Dayong
ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (43) : 8663 - 8668
[43] Catalyst-free synthesis of α-acyloxycarboxamides in aqueous media
Paprocki, Daniel
Wilk, Monika
Madej, Arleta
Walde, Peter
Ostaszewski, Ryszard
ENVIRONMENTAL CHEMISTRY LETTERS, 2019, 17 (02) : 1011 - 1016
[44] Catalyst-Free Cycloaddition Reaction for the Synthesis of Glyconanoparticles
Kong, Na
Xie, Sheng
Zhou, Juan
Menendez, Margarita
Solis, Dolores
Park, JaeHyeung
Proietti, Giampiero
Ramstrom, Olof
Yan, Mingdi
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (41) : 28136 - 28142
[45] Efficient and catalyst-free synthesis of cellulose acetoacetates
Wuerfel, Hendryk
Kayser, Marvin
Heinze, Thomas
CELLULOSE, 2018, 25 (09) : 4919 - 4928
[46] Green and catalyst-free synthesis of olsalazine analogs
Ibrahim, Mohamed A.
Elagawany, Mohamed
Ibrahim, Tarek S.
GREEN CHEMISTRY LETTERS AND REVIEWS, 2016, 9 (02) : 91 - 95
[47] Green, Catalyst-Free Synthesis of Mesalazine Conjugates
Ibrahim, Mohamed A.
Panda, Siva S.
Alamry, Khalid A.
Katritzky, Alan R.
SYNTHESIS-STUTTGART, 2013, 45 (23): : 3255 - 3258
[48] Efficient and catalyst-free synthesis of cellulose acetoacetates
Hendryk Würfel
Marvin Kayser
Thomas Heinze
Cellulose, 2018, 25 : 4919 - 4928
[49] Catalyst-free synthesis of α-acyloxycarboxamides in aqueous media
Daniel Paprocki
Monika Wilk
Arleta Madej
Peter Walde
Ryszard Ostaszewski
Environmental Chemistry Letters, 2019, 17 : 1011 - 1016
[50] Catalyst-free Solvothermal Synthesis of Carbon Nanotubes
Ellis, Tbomas
Paras, Christian
Stride, John A.
2008 INTERNATIONAL CONFERENCE ON NANOSCIENCE AND NANOTECHNOLOGY, 2008, : 40 - 43

← 1 2 3 4 5 →