Synthesis of N-Sulfonylamidines by Catalyst-Free Hydroamination of Ynamides and Amines

被引：18

作者：

Kong, Yulong ^{[1
]}

Yu, Lian ^{[1
]}

Cui, Yuming ^{[1
]}

Cao, Jian ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2014年 / 46卷 / 02期

基金：

中国国家自然科学基金;

关键词：

amines; sulfonamides; aminations; ONE-POT SYNTHESIS; SUBSTITUTED YNAMIDES; INTERMOLECULAR HYDROAMINATION; ELECTROPHILIC CYCLIZATION; OXIDATIVE ALKYNYLATION; EFFICIENT SYNTHESIS; TERMINAL ALKYNES; GOLD(I) COMPLEX; BOND FORMATION; AMIDATION;

D O I：

10.1055/s-0033-1340287

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel synthesis of N-sulfonylamidines by catalyst-free hydroamination of N, N-disulfonyl ynamides with amines was developed. Alkyl amines react with N, N-disulfonyl ynamides under mild conditions, whereas aryl amines require higher temperatures. Plausible mechanisms are proposed to explain this reaction.

引用

页码：183 / 188

页数：6

共 50 条

[31] Catalyst-free synthesis of acenaphthoindolopyrimidine derivatives
Nahale Kakavand
Mohammad Bayat
Yadollah Bayat
Molecular Diversity, 2023, 27 : 1785 - 1793
[32] Copper iodide nanoparticles supported on magnetic aminomethylpyridine functionalized cellulose: a new heterogeneous and recyclable nanomagnetic catalyst for facile access to N-sulfonylamidines under solvent free conditions
Ghasemi, Zarrin
Shojaei, Salman
Shahrisa, Aziz
RSC ADVANCES, 2016, 6 (61) : 56213 - 56224
[33] A catalyst-free synthesis of α-aminophosphonates in glycerol
Azizi, Kobra
Karimi, Meghdad
Heydari, Akbar
TETRAHEDRON LETTERS, 2014, 55 (52) : 7236 - 7239
[34] Catalyst-free coupling of peroxypyrroloindolenines with amines to afford stable peroxyindolenines
Zheng, Xiaoshan
Wang, Menghan
Sun, Xianbin
Gao, Yu
Chen, Haijun
ORGANIC & BIOMOLECULAR CHEMISTRY, 2025, 23 (05) : 1215 - 1218
[35] CuI incorporated magnetic iminochitosan as an efficient catalyst for the synthesis of N-sulfonylamidines possessing 2-formylpyrrole moiety and their subsequent reactions to the synthesis of isoxazole-5-one hybrid derivatives
Valizadeh, Sepideh
Ghasemi, Zarrin
Shahrisa, Aziz
Pirouzmand, Mahtab
Kabiri, Roya
REACTIVE & FUNCTIONAL POLYMERS, 2022, 171
[36] Catalyst-free Synthesis of 6-Hydroxy Indoles via the Condensation of Carboxymethyl Cyclohexadienones and Amines
Reddy, Reddy Rajasekhar
Adlak, Komalkant
Ghorai, Prasanta
JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (16): : 8426 - 8437
[37] Deoxygenative hydroboration of primary, secondary, and tertiary amides: Catalyst-free synthesis of various substituted amines
Yi, Jaeeun
Kim, Hyun Tae
Jaladi, Ashok Kumar
An, Duk Keun
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2022, 43 (01) : 129 - 132
[38] IR-SPECTROSCOPY OF AMINES .1. N-SULFONYLAMIDINES AND 3-AMINO-1,2-BENZISOTHIAZOLE-1,1-DIOXIDES
SCHWENKER, G
BOSL, K
ARCHIV DER PHARMAZIE UND BERICHTE DER DEUTSCHEN PHARMAZEUTISCHEN GESSELSCHAFT, 1970, 303 (12): : 980 - +
[39] Solvent and catalyst-free synthesis of some new aminonaphthoquinones from lawsone, ninhydrin and heteroaryl amines
Olyaei, Abolfazl
Taheri, Neda
Sadeghpour, Mahdieh
RESEARCH ON CHEMICAL INTERMEDIATES, 2021, 47 (03) : 1211 - 1219
[40] Solvent and catalyst-free synthesis of some new aminonaphthoquinones from lawsone, ninhydrin and heteroaryl amines
Abolfazl Olyaei
Neda Taheri
Mahdieh Sadeghpour
Research on Chemical Intermediates, 2021, 47 : 1211 - 1219

← 1 2 3 4 5 →