共 3 条
A Flexible Two-Fold Interpenetrated Indium MOF Exhibiting Dynamic Response to Gas Adsorption and High-Sensitivity Detection of Nitroaromatic Explosives
被引:30
|作者:
Cao, Zhen
[1
,2
]
Chen, Lian
[1
]
Li, Shengchang
[1
,4
]
Yu, Muxin
[3
]
Li, Zhijia
[1
,2
]
Zhou, Kang
[1
]
Liu, CaiPing
[1
]
Jiang, Feilong
[1
]
Hong, Maochun
[1
]
机构:
[1] Chinese Acad Sci Fuzhou, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
[3] Fujian Jiangxia Univ, Coll Elect & Informat Sci, Organ Optoelect Engn Res Ctr Fujians Univ, Fuzhou 350002, Fujian, Peoples R China
[4] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
基金:
中国国家自然科学基金;
关键词:
dynamic response;
interpenetration;
metal-organic framework;
nitroaromatic explosives detector;
METAL-ORGANIC FRAMEWORK;
COORDINATION POLYMERS;
BREATHING BEHAVIOR;
TRACE DETECTION;
IONS;
CARBOXYLATE;
SENSORS;
CLUSTER;
SERIES;
PHASE;
D O I:
10.1002/asia.201900458
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A flexible two-fold interpenetrated indium metal-organic framework InOF-23, featuring one-dimensional micro-sized channels decorated by exposed N groups, was successfully synthesized. Interestingly, InOF-23 displays unique dynamic responses to different gases (N-2, Ar, and CO2) at low and room temperatures, which indicates that it can be a good candidate for gas adsorption and separation. Furthermore, the high efficiency detection for p-nitroaniline (pNA) makes InOF-23 a potential chemosensor for nitroaromatic explosives.
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页码:3597 / 3602
页数:6
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