A Flexible Two-Fold Interpenetrated Indium MOF Exhibiting Dynamic Response to Gas Adsorption and High-Sensitivity Detection of Nitroaromatic Explosives

被引：30

作者：

Cao, Zhen ^{[1
,2
]}

Chen, Lian ^{[1
]}

Li, Shengchang ^{[1
,4
]}

Yu, Muxin ^{[3
]}

Li, Zhijia ^{[1
,2
]}

Zhou, Kang ^{[1
]}

Liu, CaiPing ^{[1
]}

Jiang, Feilong ^{[1
]}

Hong, Maochun ^{[1
]}

机构：

[1] Chinese Acad Sci Fuzhou, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China

[3] Fujian Jiangxia Univ, Coll Elect & Informat Sci, Organ Optoelect Engn Res Ctr Fujians Univ, Fuzhou 350002, Fujian, Peoples R China

[4] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2019年 / 14卷 / 20期

基金：

中国国家自然科学基金;

关键词：

dynamic response; interpenetration; metal-organic framework; nitroaromatic explosives detector; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; BREATHING BEHAVIOR; TRACE DETECTION; IONS; CARBOXYLATE; SENSORS; CLUSTER; SERIES; PHASE;

D O I：

10.1002/asia.201900458

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A flexible two-fold interpenetrated indium metal-organic framework InOF-23, featuring one-dimensional micro-sized channels decorated by exposed N groups, was successfully synthesized. Interestingly, InOF-23 displays unique dynamic responses to different gases (N-2, Ar, and CO2) at low and room temperatures, which indicates that it can be a good candidate for gas adsorption and separation. Furthermore, the high efficiency detection for p-nitroaniline (pNA) makes InOF-23 a potential chemosensor for nitroaromatic explosives.

引用

页码：3597 / 3602

页数：6

共 56 条

[1] Autoluminescent Metal-Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF [J].

Andreo, Jacopo ;

Priola, Emanuele ;

Alberto, Gabriele ;

Benzi, Paola ;

Marabello, Domenica ;

Proserpio, Davide M. ;

Lamberti, Carlo ;

Diana, Eliano .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (43) :14144-14149

[2] Pulsed spectrometer for nuclear quadrupole resonance for remote detection of nitrogen in explosives [J].

Anferov, VP ;

Mozjoukhine, GV ;

Fisher, R .

REVIEW OF SCIENTIFIC INSTRUMENTS, 2000, 71 (04) :1656-1659

[3] Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal-Organic Frameworks [J].

Aulakh, Darpandeep ;

Islamoglu, Timur ;

Bagundes, Veronica F. ;

Varghese, Juby R. ;

Duell, Kyle ;

Joy, Monu ;

Teat, Simon J. ;

Farha, Omar K. ;

Wriedt, Mario .

CHEMISTRY OF MATERIALS, 2018, 30 (22) :8332-8342

[4]

Carrington EJ, 2017, NAT CHEM, V9, P882, DOI [10.1038/NCHEM.2747, 10.1038/nchem.2747]

[5] Strategic Construction of Highly Stable Metal-Organic Frameworks Combining Both Semi-Rigid Tetrapodal and Rigid Ditopic Linkers: Selective and Ultrafast Sensing of 4-Nitroaniline in Water [J].

Chakraborty, Gouri ;

Das, Prasenjit ;

Mandal, Sanjay K. .

ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (49) :42406-42416

[6] An anionic Na(I)-organic framework platform: separation of organic dyes and post-modification for highly sensitive detection of picric acid [J].

Chen, Di-Ming ;

Tian, Jia-Yue ;

Wang, Zhuo-Wei ;

Liu, Chun-Sen ;

Chen, Min ;

Du, Miao .

CHEMICAL COMMUNICATIONS, 2017, 53 (77) :10668-10671

[7] Multifunctional Lanthanide-Based Metal-Organic Frameworks with a Polyheterotopic Ligand: Doped with Ytterbium(III) for Luminescence Enhancement and Selective Dye Adsorption [J].

Chen, Wei ;

Fan, Ruiqing ;

Wang, Ping ;

Dong, Yuwei ;

Yang, Yulin .

CHEMISTRY-AN ASIAN JOURNAL, 2018, 13 (16) :2126-2134

[8] Environmentally friendly synthesis of flexible MOFs M(NA)2 (M = Zn, Co, Cu, Cd) with large and regenerable ammonia capacity [J].

Chen, Yang ;

Shan, Bohan ;

Yang, Chengyin ;

Yang, Jiangfeng ;

Li, Jinping ;

Mu, Bin .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (21) :9922-9929

[9] Optical explosives detection: from color changes to fluorescence turn-on [J].

Germain, Meaghan E. ;

Knapp, Michael J. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (09) :2543-2555

[10]

Håkansson K, 2000, J MASS SPECTROM, V35, P337, DOI 10.1002/(SICI)1096-9888(200003)35:3<337::AID-JMS940>3.0.CO

← 1 2 3 4 5 6 →