A Flexible Two-Fold Interpenetrated Indium MOF Exhibiting Dynamic Response to Gas Adsorption and High-Sensitivity Detection of Nitroaromatic Explosives

被引:30
|
作者
Cao, Zhen [1 ,2 ]
Chen, Lian [1 ]
Li, Shengchang [1 ,4 ]
Yu, Muxin [3 ]
Li, Zhijia [1 ,2 ]
Zhou, Kang [1 ]
Liu, CaiPing [1 ]
Jiang, Feilong [1 ]
Hong, Maochun [1 ]
机构
[1] Chinese Acad Sci Fuzhou, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
[3] Fujian Jiangxia Univ, Coll Elect & Informat Sci, Organ Optoelect Engn Res Ctr Fujians Univ, Fuzhou 350002, Fujian, Peoples R China
[4] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
基金
中国国家自然科学基金;
关键词
dynamic response; interpenetration; metal-organic framework; nitroaromatic explosives detector; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; BREATHING BEHAVIOR; TRACE DETECTION; IONS; CARBOXYLATE; SENSORS; CLUSTER; SERIES; PHASE;
D O I
10.1002/asia.201900458
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A flexible two-fold interpenetrated indium metal-organic framework InOF-23, featuring one-dimensional micro-sized channels decorated by exposed N groups, was successfully synthesized. Interestingly, InOF-23 displays unique dynamic responses to different gases (N-2, Ar, and CO2) at low and room temperatures, which indicates that it can be a good candidate for gas adsorption and separation. Furthermore, the high efficiency detection for p-nitroaniline (pNA) makes InOF-23 a potential chemosensor for nitroaromatic explosives.
引用
收藏
页码:3597 / 3602
页数:6
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