4,6-Connected fsb Topology Networks Obtained through Two-Step Crystal Engineering of Decorated Trigonal Prismatic Nodes

被引：12

作者：

Schoedel, Alexander ^{[1
]}

Jaquier, Michael ^{[1
]}

Boyette, Wesley ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Eddaoudi, Mohamed ^{[1
,2
]}

Zaworotko, Michael J. ^{[1
,3
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] King Abdullah Univ Sci & Technol, Thuwal 239556900, Saudi Arabia

[3] Univ Limerick, Dept Chem & Environm Sci, Limerick, Ireland

来源：

CRYSTAL GROWTH & DESIGN | 2014年 / 14卷 / 05期

关键词：

METAL-ORGANIC FRAMEWORKS; BUILDING-BLOCKS; DESIGN; MOLECULES; CHEMISTRY;

D O I：

10.1021/cg500205f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A two-step crystal engineering strategy has been utilized to synthesize a new and versatile class of metal organic materials, the first to exhibit 4,6-connected fsb topology. The new fsb networks are constructed from simple and inexpensive nodes (4-connected Zn(CO2)(py)(2) tetrahedra; 6-connected Cr(mu(3)-O)(RCO2)(6) trigonal prisms) and linker ligands (isonicotinate and various dicarboxylates). Further, since interpenetration is precluded, they can exhibit extra-large void volumes. These fsb nets are prototypal for what should ultimately become a large family of related structures given the ready availability of functionalized and/or expanded variants of both linker ligands. The fsb nets described herein therefore represent platforms or blueprints for a new family of ultrahigh surface area porous materials.

引用

页码：2115 / 2117

页数：3

共 42 条

[11] Crystal engineering of NLO materials based on metal-organic coordination networks [J].