Manganese(III)-catalysed oxidation of sulphides with sodium chlorite in an aprotic solvent in the presence of alumina

被引：41
作者：
Hirano, M
Yakabe, S
Clark, JH
Kudo, H
Morimoto, T
机构：
[1] UNIV YORK, DEPT CHEM, YORK YO1 5DD, N YORKSHIRE, ENGLAND
[2] TOKYO UNIV AGR & TECHNOL, FAC TECHNOL, DEPT APPL CHEM, KOGANEI, TOKYO 184, JAPAN
来源：
SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 10期
关键词：
D O I：
10.1080/00397919608003540
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A wide variety of sulphides can be readily converted to the corresponding sulphoxides in good to excellent yields by treatment with a combination of sodium chlorite, (salen)manganese(III) complex, and chromatographic alumina in dichloromethane under mild and neutral conditions.
引用
收藏
页码：1875 / 1886
页数：12
相关论文
共 34 条
[1]  
ARORA CS, 1983, CHEM IND-LONDON, P318
[2]   SIMPLE AND FACILE OXIDATION OF ALDEHYDES TO CARBOXYLIC-ACIDS [J].
BABU, BR ;
BALASUBRAMANIAM, KK .
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1994, 26 (01) :123-125
[3]   OXIDATION OF ALPHA,BETA-UNSATURATED ALDEHYDES [J].
BAL, BS ;
CHILDERS, WE ;
PINNICK, HW .
TETRAHEDRON, 1981, 37 (11) :2091-2096
[4]  
Clark J.H., 1994, CATALYSIS ORGANIC RE
[5]  
CLARK JH, 1992, SUPPORTED REAGENTS P
[6]   ACETOGENIN SYNTHESIS - ORGANOCOPPER REAGENTS, ANIONS OF 1,3-DITHIANS AND OF PROTECTED CYANOHYDRINS AS INTERMEDIATES IN KETIDE SIDE-CHAIN SYNTHESIS [J].
COLOMBO, L ;
GENNARI, C ;
SANTANDREA, M ;
NARISANO, E ;
SCOLASTICO, C .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1980, (01) :136-140
[7]   SELECTIVE OXIDATION OF ALDEHYDES TO CARBOXYLIC-ACIDS WITH SODIUM-CHLORITE HYDROGEN-PEROXIDE [J].
DALCANALE, E ;
MONTANARI, F .
JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (04) :567-569
[8]   A PRACTICAL, HIGHLY ENANTIOSELECTIVE SYNTHESIS OF THE TAXOL SIDE-CHAIN VIA ASYMMETRIC CATALYSIS [J].
DENG, L ;
JACOBSEN, EN .
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (15) :4320-4323
[9]  
FLOOR M, 1989, RECL TRAV CHIM PAY B, V108, P384
[10]  
HAINES AH, 1984, FIESER FIESERS REAGE, V11, P482
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