Synthesis and NMR elucidation of four novel 2-(trimethylsilyl)ethyl glycosides

被引：2
作者：
Qu, Huanhuan [1 ,2 ]
Sun, Wenji [2 ]
Zhang, Yanyan [1 ]
Sollogoub, Matthieu [1 ]
Zhang, Yongmin [1 ]
机构：
[1] Univ Paris 06, CNRS, Inst Parisien Chim Mol, UMR 7201, F-75005 Paris, France
[2] NW Univ Xian, Biomed Key Lab Shaanxi Prov, Xian 710069, Peoples R China
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2014年 / 40卷 / 04期
关键词：
Total synthesis; Structure elucidation; Glycosides; NMR spectroscopy; Oligosaccharides; CHEMICAL-SYNTHESIS; GLYCOSYLATION; OLIGOSACCHARIDES; TRANSFORMATION;
D O I：
10.1007/s11164-013-1060-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four novel 2-(trimethylsilyl)ethyl glycosides have been synthesized by a short and efficient route starting from d-glucose. Their structures were elucidated by applying high-resolution mass spectra, and one-dimensional and two-dimensional NMR techniques. These glycosides were prepared and used as intermediate building blocks in the scheme developed for oligosaccharide construction.
引用
收藏
页码：1557 / 1564
页数：8
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