Effect of metallic phase species on the corrosion resistance of 17M/(10NiO-NiFe2O4) cermet inert anode of aluminum electrolysis

被引:9
作者
Lai, Yan-qing [1 ]
Li, Xin-zheng [1 ]
Li, Jie [1 ]
Tian, Zhong-liang [1 ]
Zhang, Gang [1 ]
Liu, Ye-xiang [1 ]
机构
[1] Cent S Univ, Sch Met Sci & Engn, Changsha 410083, Peoples R China
来源
JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY | 2006年 / 13卷 / 03期
关键词
inert anode; NiFe2O4; based cermet; metallic phase species; corrosion resistance;
D O I
10.1007/s11771-006-0128-z
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
NiFe2O4-based cermet inert anodes with metallic phase compositions of Cu, Ni and 85Cu15Ni were prepared by cold pressing- sintering. Their corrosion resistance was also investigated in Na3AlF6-Al2O3 melts. The results show that the metallic phase species in cermets have no effect on the concentration of impurities in bath during electrolysis, the total steady-state concentration of impurities is almost the same, i.e. between 4.12 x 10(-4) -4.80 X 10(-4). There exists metal preferential corrosion for the cermet inert anode with metal Ni as metallic phase. For NiFe2O4-based cermets, the cermet with metal Cu as metallic phase exhibits better corrosion resistance than the others.
引用
收藏
页码:214 / 218
页数:5
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