Sol gel deposited Sb doped SnO2 as transparent anode for OLED:: process, patterning and hole injection characteristics

被引:1
|
作者
Vaufrey, D [1 ]
Ben Khalifa, M [1 ]
Besland, MP [1 ]
Sandu, C [1 ]
Blanchin, MG [1 ]
Teodorescu, V [1 ]
Roger, JA [1 ]
Tardy, J [1 ]
机构
[1] Ecole Cent Lyon, Lab Elect Optoelect & Microsyst, CNRS, UMR 5512, F-69131 Ecully, France
来源
ORGANIC LIGHT-EMITTING MATERIALS AND DEVICES V | 2002年 / 4464卷
关键词
SnO2; sol-gel; RIE; OLED;
D O I
10.1117/12.457464
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
This paper reports on the potentialities of sol-gel deposited Sb doped SnO2 (TO) as a new transparent conducting oxide (TCO) for anode in organic light emitting diodes (OLED). Multilayered films with transparency over 85% and resistivity lower than 5 10(-3) Omega-cm were obtained. Structural observations by Transmission Electron Microscopy (TEM) show that the films are nanocrystallized. Smaller and more uniform grains are obtained upon rapid thermal annealing. Atomic Force Microscopy (AIM) imaging shows the surface roughness does not exceed 20 Angstrom. TO films are very stable and cannot be chemically etched. Anode patterning by reactive ion etching (RIE) in a Methane-Hydrogen plasma has been experienced and is described. Typical etching around 250 Angstrom/min were obtained. TO/PEDOT/PVK/Al hole only diodes were realized to assess sot gel TO films as hole injection electrodes. Devices with threshold voltages of 6 volts were obtained. A comparison with ITO deposited by low temperature cathodic sputtering is given.
引用
收藏
页码:103 / 112
页数:10
相关论文
共 50 条
  • [21] Synthesis and characterization of the doped/co-doped SnO2 nanoparticles by the sol-gel method
    Unal, Fatma Aydin
    INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2025, 22 (01)
  • [22] Size controlled and optical properties of Zn- doped SnO2 nanoparticles via sol-gel process
    Gajendiran, J.
    Rajendran, V.
    OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 2011, 5 (1-2): : 44 - 48
  • [23] Reactive ion etching of sol-gel-processed SnO2 transparent conducting oxide as a new material for organic light emitting diodes
    Vaufrey, D
    Ben Khalifa, M
    Besland, MP
    Sandu, C
    Blanchin, MG
    Teodorescu, V
    Roger, JA
    Tardy, J
    SYNTHETIC METALS, 2002, 127 (1-3) : 207 - 211
  • [24] Densification and crystallization of SnO2: Sb sol-gel films using excimer laser annealing
    Sandu, CS
    Teodorescu, VS
    Ghica, C
    Canut, B
    Blanchin, MG
    Roger, JA
    Brioude, A
    Bret, T
    Hoffmann, P
    Garapon, C
    APPLIED SURFACE SCIENCE, 2003, 208 : 382 - 387
  • [25] W doped SnO2 growth via sol-gel routes and characterization: Nanocubes
    Keskenler, Eyup Fahri
    Turgut, Guven
    Aydin, Serdar
    Dogan, Seydi
    OPTIK, 2013, 124 (21): : 4827 - 4831
  • [26] Sol-Gel Processed Yttrium-Doped SnO2 Thin Film Transistors
    Lee, Changmin
    Lee, Won-Yong
    Lee, Hyunjae
    Ha, Seunghyun
    Bae, Jin-Hyuk
    Kang, In-Man
    Kang, Hongki
    Kim, Kwangeun
    Jang, Jaewon
    ELECTRONICS, 2020, 9 (02)
  • [27] Sol-gel derived Sb-doped SnO2/SiO2 nano-composite thin films for gas sensors
    Gu, Zhengtian
    Liang, Peihui
    Zhang, Weiqing
    MICRO- AND NANOELECTRONICS 2005, 2006, 6260
  • [28] Electric and morphologic properties of SnO2 films prepared by modified sol-gel process
    Dal Santos, MA
    Antunes, AC
    Ribeiro, C
    Borges, CPF
    Antunes, SRM
    Zara, AJ
    Pianaro, SA
    MATERIALS LETTERS, 2003, 57 (28) : 4378 - 4381
  • [29] IrO2/SnO2 electrodes:: prepared by sol-gel process and their electrocatalytic for pyrocatechol
    Liu, Y
    Li, ZY
    Li, JH
    ACTA MATERIALIA, 2004, 52 (03) : 721 - 727
  • [30] Pore Size Distribution of Unsupported SnO2 Membranes Prepared by Sol-Gel Process
    de Souza Brito, Giancarlo Esposito
    Pulcinelli, Sandra Helena
    Santilli, Celso Valentim
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1994, 2 (1-3) : 575 - 579