N-(3-Nitrobenzylidene)aniline

被引:3
作者
Zaheer, Muhammad [1 ]
Akhter, Zareen [1 ]
Bolte, Michael [2 ]
Siddiqi, Humaira M. [1 ]
机构
[1] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
[2] Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808036970
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C13H10N2O2, a Schiff base derivative, the dihedral angle between the two aromatic rings is 31.58 (3)degrees. The C=N double bond is essentially coplanar with the nitrophenyl ring. The torsion angle of the imine double bond is 175.97 (13)degrees, indicating that the C=N double bond is in a trans configuration. The crystal structure is stabilized by C-H center dot center dot center dot O contacts and pi-pi interactions (centroid-centroid distances of 3.807 and 3.808 angstrom).
引用
收藏
页码:O2381 / U2758
页数:11
相关论文
共 16 条
[1]   Nickel-catalyzed oxidations: From hydrocarbons to DNA [J].
Burrows, CJ ;
Muller, JG ;
Poulter, GT ;
Rokita, SE .
ACTA CHEMICA SCANDINAVICA, 1996, 50 (04) :337-344
[2]   Catalytic effect of transition metal(II)-N,N′-bis(naphthaldehyde) diimines on reduction of thionyl chloride [J].
Choi, YK ;
Kim, WS ;
Chung, KI ;
Chung, MW ;
Nam, HP .
MICROCHEMICAL JOURNAL, 2000, 65 (01) :3-15
[3]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[4]   Saccharide-accelerated hydrolysis of boronic acid imines [J].
Hartley, JH ;
Phillips, MD ;
James, TD .
NEW JOURNAL OF CHEMISTRY, 2002, 26 (09) :1228-1237
[5]   ANTITUMOR ACTIVITIES OF SOME SCHIFF BASES [J].
HODNETT, EM ;
MOONEY, PD .
JOURNAL OF MEDICINAL CHEMISTRY, 1970, 13 (04) :786-&
[6]  
LINDOY LF, 1989, CHEM MACROCYCLIC LIG
[7]  
MARUYAMA K, 1995, TETRAHEDRON LETT, V36, P5609
[8]   Facile and efficient method for preparation of Schiff bases catalyzed by P2O5/SiO2 under free solvent conditions [J].
Naeimi, Hossein ;
Sharghi, Hashem ;
Salimi, Fariba ;
Rabiei, Khadijeh .
HETEROATOM CHEMISTRY, 2008, 19 (01) :43-47
[9]   Novel dinuclear manganese(III) complexes with tridentate and bridging tetradentate Schiff base ligands: Preparation, properties and catalase-like function [J].
Nakamura, T ;
Niwa, K ;
Fujiwara, M ;
Matsushita, T .
CHEMISTRY LETTERS, 1999, (10) :1067-1068
[10]   Syntheses, solubilities and oxygen absorption properties of new cobalt(II) Schiff-base complexes [J].
Park, S ;
Mathur, VK ;
Planalp, RP .
POLYHEDRON, 1998, 17 (2-3) :325-330