Polarized absorption and emission of ordered self-assembled porphyrin rings

被引：54
作者：
Jeukens, CRLPN
Lensen, MC
Wijnen, FJP
Elemans, JAAW
Christianen, PCM
Rowan, AE
Gerritsen, JW
Nolte, RJM
Maan, JC
机构：
[1] Univ Nijmegen, HFML, High Field Magnet Lab, NSRIM, NL-6525 ED Nijmegen, Netherlands
[2] Univ Nijmegen, Dept Organ Chem, NSRIM, NL-6525 ED Nijmegen, Netherlands
[3] Univ Nijmegen, Dept Solid State Phys, NSRIM, NL-6525 ED Nijmegen, Netherlands
来源：
NANO LETTERS | 2004年 / 4卷 / 08期
关键词：
D O I：
10.1021/nl049363d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Self-assembled rings (with diameters of 0.1-2.0 mum) consisting of porphyrin dodecamer molecules are formed by evaporating chloroform solutions on glass substrates. Fluorescence microscopy experiments on individual rings reveal a strongly polarized optical absorption and emission. Quantitative analysis of the fluorescence images evidences the high degree of order within the rings, consisting of radially oriented columnar stacks of porphyrin dodecamers, and the absence of energy transport along the rings on length scales resolved by fluorescence microscopy.
引用
收藏
页码：1401 / 1406
页数：6
相关论文
共 34 条
  • [1] Optical properties of gold nanorings -: art. no. 057401
    Aizpurua, J
    Hanarp, P
    Sutherland, DS
    Käll, M
    Bryant, GW
    de Abajo, FJG
    [J]. PHYSICAL REVIEW LETTERS, 2003, 90 (05) : 4
  • [2] Optically active organic microrings
    Balzer, F
    Beermann, J
    Bozhevolnyi, SI
    Simonsen, AC
    Rubahn, HG
    [J]. NANO LETTERS, 2003, 3 (09) : 1311 - 1314
  • [3] ELECTRONIC-SPECTRUM OF PORPHYRINS - CS-INDO-CI STUDY
    BARALDI, I
    CARNEVALI, A
    PONTERINI, G
    VANOSSI, D
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1995, 333 (1-2): : 121 - 133
  • [4] Three-dimensional orientations of polymer-bound single molecules
    Bartko, AP
    Dickson, RM
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (16): : 3053 - 3056
  • [5] Hidden symmetries in the energy levels of excitonic 'artificial atoms'
    Bayer, M
    Stern, O
    Hawrylak, P
    Fafard, S
    Forchel, A
    [J]. NATURE, 2000, 405 (6789) : 923 - 926
  • [6] Hexakis porphyrinato benzenes. A new class of porphyrin arrays
    Biemans, HAM
    Rowan, AE
    Verhoeven, A
    Vanoppen, P
    Latterini, L
    Foekema, J
    Schenning, APHJ
    Meijer, EW
    de Schryver, FC
    Nolte, RJM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (43) : 11054 - 11060
  • [7] De Serio M, 2003, TRAC-TREND ANAL CHEM, V22, P70, DOI 10.1016/S0165-9936(03)00201-2
  • [8] Near-field scanning optical microscopy
    Dunn, RC
    [J]. CHEMICAL REVIEWS, 1999, 99 (10) : 2891 - +
  • [9] Mechanical and optical manipulation of porphyrin rings at the submicrometre scale
    Foubert, P
    Vanoppen, P
    Martin, M
    Gensch, T
    Hofkens, J
    Helser, A
    Seeger, A
    Taylor, RM
    Rowan, AE
    Nolte, RJM
    De Schryver, FC
    [J]. NANOTECHNOLOGY, 2000, 11 (01) : 16 - 23
  • [10] Grant I.S., 1990, ELECTROMAGNETISM
1234