catena-Poly[[diiodozinc(II)]-μ-4,4′-bipyridine-κ2N:N′]

被引：4

作者：

Fan, L. -Q. ^{[1
]}

Wu, J. -H. ^{[1
]}

机构：

[1] Huaqiao Univ, Inst Mat Phys Chem, Fujian 362021, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷 / 11期

关键词：

D O I：

10.1107/S0108270106039965

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [ ZnI2( bipy)] n ( bipy is 4,4'-bipyridine, C10H8N2), has been prepared by the hydrothermal reaction of ZnI2 and bipy at 433 K. Each Zn atom is coordinated by two N atoms from two different bipy ligands and by two I atoms in a distorted tetrahedral geometry, with Zn - N distances ranging from 2.068 ( 7) to 2.101 ( 8) angstrom and Zn - I distances ranging from 2.5471 ( 13) to 2.5673 ( 13) angstrom. The molecular structure features a zigzag polymeric chain. Face- to- face pi-pi stacking interactions between adjacent bipy ligands stabilize the structure.

引用

页码：M548 / M549

页数：2

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