Practical New Strategies for Immobilising Ruthenium Alkylidene Complexes: Part I IMMOBILISATION VIA PHOSPHANE, ALKYLIDENE AND N-HETEROCYCLIC CARBENE LIGANDS

被引：18
作者：
Dragutan, Ileana [1 ]
Dragutan, Valerian [1 ]
机构：
[1] Romanian Acad, Inst Organ Chem Costin Nenitescu, Bucharest 060023, Romania
来源：
PLATINUM METALS REVIEW | 2008年 / 52卷 / 02期
关键词：
D O I：
10.1595/147106708X297477
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The paper critically presents various routes for immobilising ruthenium alkylidene complexes through their ligands. This part (Part I) describes immobilisation via coordinating/ actor ligands (phosphane/alkylidene), and established ancillary ligands such as N-heterocyclic carbenes. Other ligands commonly encountered in immobilisation protocols, such as Schiff bases, arenes, anionic ligands and specifically tagged (ionic liquid tag, fluoro tag) substituents will be the topic of Part II. Selected applications of some of these ruthenium complexes in olefin metathesis reactions are highlighted where they are particularly advantageous.
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页码：71 / 82
页数：12
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