Synthesis and pH dependent optical properties of gold nanoparticles capped with mercaptopropionic acid

被引:12
作者
Liu, ST [1 ]
Zhu, T [1 ]
Wang, YC [1 ]
Liu, ZF [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, Ctr Nanoscale Sci & Technol, Beijing 100871, Peoples R China
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1999年 / 337卷
基金
中国国家自然科学基金;
关键词
gold nanoparticles; mercaptopropionic acid; HRTEM; UV-visible spectroscopy;
D O I
10.1080/10587259908023423
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A simple method is reported for preparing gold nanoparticles capped with 3-mercaptopropionic acid(MPA). The capped Au nanoparticles can be isolated as a dark brown solid which can be re-dispersed in sodium hydrate solution. The average size of nanoparticles is 4.9+/-0.7 nm, determined by HRTEM. The surface plasmon band of Au nanoparticles around 520nm was found red-shifted together with a slight damping and broadening, as the pH of the colloid is adjusted from 11 to 3.5. Such a shift is attributed to the pH dependent surface charge of the nanoparticles.
引用
收藏
页码:245 / 248
页数:4
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