Palladium nanoparticles catalyzed Sonogashira reactions for the one-pot synthesis of symmetrical and unsymmetrical diarylacetylenes

被引：19

作者：

Mandali, Pavan Kumar ^{[1
]}

Chand, Dillip Kumar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

CATALYSIS COMMUNICATIONS | 2014年 / 47卷

关键词：

Sonogashira reactions; Palladium nanoparticles; Trimethylsilylacetylene; Diarylacetylenes; METAL-ORGANIC FRAMEWORKS; CROSS-COUPLING REACTIONS; HIGHLY-ACTIVE CATALYSTS; ARYL IODIDES; FACILE SYNTHESIS; HECK REACTIONS; EFFICIENT; DIARYLALKYNES; CARBON; ALKYNYLSILANES;

D O I：

10.1016/j.catcom.2013.12.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A variety of symmetrical and unsymmetrical diarylacetylenes are synthesized by ligand-free palladium nanoparticles catalyzed copper-free and amine-free Sonogashira cross-coupling reactions between aryl iodides and trimethylsilylacetylene (TMSA) under mild reaction conditions. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：40 / 44

页数：5

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