[Pd(IPr*OMe)(cin)Cl] (cin = Cinnamyl): A Versatile Catalyst for C-N and C-C Bond Formation

被引：82
|
作者：
Bastug, Gulluzar [1 ]
Nolan, Steven P. [1 ]
机构：
[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland
来源：
ORGANOMETALLICS | 2014年 / 33卷 / 05期
关键词：
CROSS-COUPLING REACTIONS; ORTHO-SUBSTITUTED BIARYLS; HETEROCYCLIC CARBENE LIGANDS; SUZUKI-MIYAURA COUPLINGS; PD-PEPPSI-IPENT; BUCHWALD-HARTWIG; GRIGNARD-REAGENTS; (NHC)PD(ALLYL)CL NHC; ARYL CHLORIDES; AMINATION;
D O I：
10.1021/om500026s
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Pd(IPr*(OMe))(cin)(Cl)] provides high catalytic activity for Buchwald-Hartwig cross-coupling reactions of sterically demanding aryl chlorides with sterically hindered and deactivated aniline derivatives. This catalyst also proved efficient in Suzuki-Miyaura reactions, thus allowing the preparation of tetra-ortho-substituted biaryls. The Kumada-Corriu coupling has also been investigated using this palladium N-heterocyclic carbene (NHC) catalyst.
引用
收藏
页码：1253 / 1258
页数：6
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