A brief review of para-xylene oxidation to terephthalic acid as a model of primary C-H bond activation

被引：44
作者：
Fadzil, Nor Aqilah Mohd [1 ]
Rahim, Mohd Hasbi Ab. [1 ]
Maniam, Gaanty Pragas [1 ]
机构：
[1] Univ Malaysia Pahang, Fac Ind Sci & Technol, Gambang Kuantan 26300, Pahang, Malaysia
来源：
CHINESE JOURNAL OF CATALYSIS | 2014年 / 35卷 / 10期
关键词：
Heterogeneous catalyst; Optimisation; Oxidation; para-Xylene; Promoter; Terephthalic acid; LIQUID-PHASE OXIDATION; RESPONSE-SURFACE METHODOLOGY; P-XYLENE; AEROBIC OXIDATION; CATALYTIC-OXIDATION; SELECTIVE OXIDATION; HIGH-TEMPERATURE; CARBON-DIOXIDE; N-HYDROXYPHTHALIMIDE; PROCESS OPTIMIZATION;
D O I：
10.1016/S1872-2067(14)60193-5
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The oxidation of para-xylene to terephthalic acid has been commercialised as the AMOCO process (Co/Mn/Br) that uses a homogeneous catalyst of cobalt and manganese together with a corrosive bromide compound as a promoter. This process is conducted in acidic medium at a high temperature (175-225 degrees C). Concerns over environmental and safety issues have driven studies to find milder oxidation reactions of para-xylene. This review discussed past and current progress in the oxidation of para-xylene process. The discussion concentrates on the approach of green chemistry including (1) using heterogeneous catalysts with promising high selectivity and mild reaction condition, (2) application of carbon dioxide as a co-oxidant, and (3) application of alternative promoters. The optimisation of para-xylene oxidation was also outlined. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：1641 / 1652
页数：12
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