Water and chemical savings in cooling towers by using membrane capacitive deionization

被引:65
作者
van Limpt, B. [1 ]
van der Wal, A. [1 ,2 ]
机构
[1] Voltea BV, NL-2171 AE Sassenheim, Netherlands
[2] Wageningen Univ, Dept Environm Technol, NL-6708 WG Wageningen, Netherlands
关键词
Membrane capacitive deionization; Cooling towers; Preferential ion uptake; Water savings; Chemical savings; EXCHANGE MEMBRANES; ENERGY-CONSUMPTION; HYDRATED IONS; ELECTRODIALYSIS; PERMSELECTIVITY; DESALINATION; SELECTIVITY; ELECTRODES; PERMEATION;
D O I
10.1016/j.desal.2013.12.022
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Membrane capacitive deionization (MCDI) is a water desalination technology based on applying a voltage difference between two oppositely placed porous carbon electrodes. In front of each electrode, an ion exchange membrane is positioned, and between them, a spacer is situated, which transports the water to be desalinated. In this study we determined the water and chemical savings that can be achieved in a cooling tower by desalinating the feed water stream with a full-scale MCDI system. By monitoring the water use of the cooling tower, and comparing this to a scenario without MCDI, chemical savings up to 85% could be achieved. Additionally, water savings up to 28%, and waste water savings up to 48% could be achieved. MCDI energy use for desalination of cooling tower feed water was between 0.1 and 0.2 kWh per cubic meter of produced desalinated water. Preferential uptake of chloride and calcium was observed, which lowers the risk of scaling and corrosion in the cooling tower and allows for further chemical and water savings. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:148 / 155
页数:8
相关论文
共 29 条
[1]   Membrane treatment of side-stream cooling tower water for reduction of water usage [J].
Altman, Susan J. ;
Jensen, Richard P. ;
Cappelle, Malynda A. ;
Sanchez, Andres L. ;
Everett, Randy L. ;
Anderson, Howard L., Jr. ;
McGrath, Lucas K. .
DESALINATION, 2012, 285 :177-183
[2]   Capacitive deionization as an electrochemical means of saving energy and delivering clean water. Comparison to present desalination practices: Will it compete? [J].
Anderson, Marc A. ;
Cudero, Ana L. ;
Palma, Jesus .
ELECTROCHIMICA ACTA, 2010, 55 (12) :3845-3856
[3]   Theory of membrane capacitive deionization including the effect of the electrode pore space [J].
Biesheuvel, P. M. ;
Zhao, R. ;
Porada, S. ;
van der Wal, A. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 360 (01) :239-248
[4]   Membrane capacitive deionization [J].
Biesheuvel, P. M. ;
van der Wal, A. .
JOURNAL OF MEMBRANE SCIENCE, 2010, 346 (02) :256-262
[5]   Dynamic Adsorption/Desorption Process Model for Capacitive Deionization [J].
Biesheuvel, P. M. ;
van Limpt, B. ;
van der Wal, A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (14) :5636-5640
[6]   Energy Recovery in Membrane Capacitive Deionization [J].
Dlugolecki, Piotr ;
van der Wal, Albert .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2013, 47 (09) :4904-4910
[7]   A comparative study of electrosorption selectivity of ions by activated carbon electrodes in capacitive deionization [J].
Hou, Chia-Hung ;
Huang, Cheng-Ye .
DESALINATION, 2013, 314 :124-129
[8]   Enhanced desalination efficiency in capacitive deionization with an ion-selective membrane [J].
Kim, Yu-Jin ;
Choi, Jae-Hwan .
SEPARATION AND PURIFICATION TECHNOLOGY, 2010, 71 (01) :70-75
[9]  
Kinoshita K., 1988, CARBON ELECTROCHEMIC
[10]   ACTION OF SODIUM SILICATE AS A CORROSION INHIBITOR IN WATER PIPING [J].
LEHRMAN, L ;
SHULDENER, HL .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1952, 44 (08) :1765-1769