Assembly and decomposition of building blocks to analyze polymer NEXAFS spectra

被引：0
作者：
Pettersson, LGM
Agren, H
Schurmann, BL
Lippitz, A
Unger, WES
机构：
[1] LINKOPING UNIV, INST PHYS & MEASUREMENT TECHNOL, S-58183 LINKOPING, SWEDEN
[2] BUNDESANSTALT MAT FORSCH & PRUFUNG, D-12200 BERLIN, GERMANY
来源：
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY | 1997年 / 63卷 / 03期
关键词：
building-block; polymer; NEXAFS; static exchange; X-ray absorption;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The poly(ethylene-terephthalate) and poly(bisphenol-A-carbonate) compounds are used to illustrate the possibilities and Limitations of building-block analysis of polymer near-edge X-ray absorption spectra. Experimental spectra obtained for thin polymer films are analyzed using theoretical static exchange calculations of C-1s and O-1s excitation spectra on model molecules selected as possible building blocks. (C) 1997 John Wiley & Sons, Inc.
引用
收藏
页码：749 / 765
页数：17
相关论文
共 54 条
[31]   CALCULATION OF NEAR-EDGE X-RAY-ABSORPTION SPECTRA OF MOLECULES AND POLYMERS BY A GREEN-FUNCTION METHOD [J].
LIEGENER, C ;
AGREN, H .
PHYSICAL REVIEW B, 1993, 48 (02) :789-798
[32]   Surface analysis of metallized poly(bisphenol A carbonate) films by X-ray absorption spectroscopy (NEXAFS) [J].
Lippitz, A ;
Koprinarov, I ;
Friedrich, JF ;
Unger, WES ;
Weiss, K ;
Woll, C .
POLYMER, 1996, 37 (14) :3157-3160
[33]   Surface analysis of partially crystalline and amorphous poly(ethylene terephthalate) samples by X-ray absorption spectroscopy (NEXAFS) [J].
Lippitz, A ;
Friedrich, JF ;
Unger, WES ;
Schertel, A ;
Woll, C .
POLYMER, 1996, 37 (14) :3151-3155
[34]   SUB-ELECTRON-VOLT CHEMICAL-SHIFTS AND STRONG INTERFERENCE EFFECTS MEASURED IN THE RESONANCE X-RAY-SCATTERING SPECTRA OF ANILINE [J].
LUO, Y ;
AGREN, H ;
GUO, JH ;
SKYTT, P ;
WASSDAHL, N ;
NORDGREN, J .
PHYSICAL REVIEW A, 1995, 52 (05) :3730-3736
[35]   HIGH-RESOLUTION K-SHELL PHOTOABSORPTION MEASUREMENTS OF SIMPLE MOLECULES [J].
MA, Y ;
CHEN, CT ;
MEIGS, G ;
RANDALL, K ;
SETTE, F .
PHYSICAL REVIEW A, 1991, 44 (03) :1848-1858
[36]   FERMI-LEVEL LOWERING AND THE CORE EXCITON SPECTRUM OF INTERCALATED GRAPHITE [J].
MELE, EJ ;
RITSKO, JJ .
PHYSICAL REVIEW LETTERS, 1979, 43 (01) :68-71
[37]   POLARIZED XANES STUDIES OF ORIENTED POLYETHYLENE AND FLUORINATED POLYETHYLENES [J].
OHTA, T ;
SEKI, K ;
YOKOYAMA, T ;
MORISADA, I ;
EDAMATSU, K .
PHYSICA SCRIPTA, 1990, 41 (01) :150-153
[38]   NEXAFS STUDIES OF COMPLEX ALCOHOLS AND CARBOXYLIC-ACIDS ON THE SI(111)(7X7) SURFACE [J].
OUTKA, DA ;
STOHR, J ;
MADIX, RJ ;
ROTERMUND, HH ;
HERMSMEIER, B ;
SOLOMON, J .
SURFACE SCIENCE, 1987, 185 (1-2) :53-74
[39]   ORIENTATION OF ARACHIDATE CHAINS IN LANGMUIR-BLODGETT MONOLAYERS ON SI(111) [J].
OUTKA, DA ;
STOHR, J ;
RABE, JP ;
SWALEN, JD ;
ROTERMUND, HH .
PHYSICAL REVIEW LETTERS, 1987, 59 (12) :1321-1324
[40]   PHOTOABSORPTION IN CARBON-MONOXIDE - STIELTJES-TCHEBYCHEFF CALCULATIONS IN SEPARATED-CHANNEL STATIC-EXCHANGE APPROXIMATION [J].
PADIAL, N ;
CSANAK, G ;
MCKOY, BV ;
LANGHOFF, PW .
JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (07) :2992-3004
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