[MO(CH3)6] and [Mo(CH3)7]-

被引：0

作者：

Roessler, B ^{[1
]}

Seppelt, K ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Anorgan & Analyt Chem, D-14195 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2000年 / 39卷 / 07期

关键词：

methyl complexes; molybdenum; structure elucidation;

D O I：

10.1002/(SICI)1521-3773(20000403)39:7<1259::AID-ANIE1259>3.0.CO;2-Y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A C(3v)-distorted structure is adopted by the nearly trigonal-prismatic [Mo(CH3)6] molecules in the crystal (see picture). The octahedron, on which so much complex chemistry is based, is in this case the most unsuitable structure principle. The [Mo(CH3)6] ion avoids interligand angles of 180°as does the [Mo(CH3)7]- ion with a seven-coordinate Mo center and capped octahedral structure.

引用

页码：1259 / +

页数：4

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