Nano-CoFe2O4 supported molybdenum as an efficient and magnetically recoverable catalyst for a one-pot, four-component synthesis of functionalized pyrroles

被引:99
作者
Li, Bao-Le [1 ]
Zhang, Mo [2 ]
Hu, Hai-Chuan [1 ]
Du, Xia [2 ]
Zhang, Zhan-Hui [1 ]
机构
[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China
[2] Hebei Normal Univ, Huihua Coll, Shijiazhuang 050091, Peoples R China
基金
中国国家自然科学基金;
关键词
ENCAPSULATED GAMMA-FE2O3 NANOPARTICLES; HIGHLY SUBSTITUTED PYRROLES; 3-COMPONENT SYNTHESIS; MULTICOMPONENT REACTIONS; SEPARABLE CATALYST; SULFONIC-ACID; CHLORIDE; CYCLIZATION; CORE; NANOCOMPOSITES;
D O I
10.1039/c3nj01368e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel magnetic nanoparticle CoFe2O4 supported Mo([CoFe2O4@SiO2-PrNH2-Mo(acac)(2)]) was prepared and found to be a highly active and efficient catalyst for a one-pot synthesis of polysubstituted pyrroles via four-component reaction of aldehydes, amines, 1,3-dicarbonyl compounds and nitromethane. The easy recovery of the catalyst and reusability, broad substrate scopes, short reaction time, high yields of products and solvent-free conditions make this protocol practical, environmentally friendly and economically attractive.
引用
收藏
页码:2435 / 2442
页数:8
相关论文
共 75 条
[1]  
Bhunia N., 2013, SYNTHESIS-STUTTGART, P1045
[2]   A New Pyrrole Synthesis via Silver(I)-Catalyzed Cycloaddition of Vinylogous Diazoester and Nitrile [J].
Billedeau, Roland J. ;
Klein, Klara R. ;
Kaplan, Daniel ;
Lou, Yan .
ORGANIC LETTERS, 2013, 15 (07) :1421-1423
[3]   Developing novel C-4 analogues of pyrrole-based antitubulin agents: weak but critical hydrogen bonding in the colchicine site [J].
Da, Chenxiao ;
Telang, Nakul ;
Hall, Kayleigh ;
Kluball, Emily ;
Barelli, Peter ;
Finzel, Kara ;
Jia, Xin ;
Gupton, John T. ;
Mooberry, Susan L. ;
Kellogg, Glen E. .
MEDCHEMCOMM, 2013, 4 (02) :417-421
[4]   One-Pot, Three-Component Synthesis of a Library of Spirooxindole-Pyrimidines Catalyzed by Magnetic Nanoparticle Supported Dodecyl Benzenesulfonic Acid in Aqueous Media [J].
Deng, Jia ;
Mo, Li-Ping ;
Zhao, Fei-Yang ;
Zhang, Zhan-Hui ;
Liu, Shou-Xin .
ACS COMBINATORIAL SCIENCE, 2012, 14 (05) :335-341
[5]   Sulfonic acid supported on hydroxyapatite-encapsulated-γ-Fe2O3 nanocrystallites as a magnetically separable catalyst for one-pot reductive amination of carbonyl compounds [J].
Deng, Jia ;
Mo, Li-Ping ;
Zhao, Fei-Yang ;
Hou, Lan-Lan ;
Yang, Li ;
Zhang, Zhan-Hui .
GREEN CHEMISTRY, 2011, 13 (09) :2576-2584
[6]   Amide- and urea-functionalized pyrroles and benzopyrroles as synthetic, neutral anion receptors [J].
Dydio, Pawel ;
Lichosyt, Dawid ;
Jurczak, Janusz .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (05) :2971-2985
[7]   Three-component access to pyrroles promoted by the CAN-silver nitrate system under high-speed vibration milling conditions: a generalization of the Hantzsch pyrrole synthesis [J].
Estevez, Veronica ;
Villacampa, Mercedes ;
Carlos Menendez, J. .
CHEMICAL COMMUNICATIONS, 2013, 49 (06) :591-593
[8]   Highly Efficient Synthesis of Polysubstituted Pyrroles via Four-Component Domino Reaction [J].
Feng, Xian ;
Wang, Qian ;
Lin, Wei ;
Dou, Guo-Lan ;
Huang, Zhi-Bin ;
Shi, Da-Qing .
ORGANIC LETTERS, 2013, 15 (10) :2542-2545
[9]   Magnetite-supported sulfonic acid: a retrievable nanocatalyst for the Ritter reaction and multicomponent reactions [J].
Gawande, Manoj B. ;
Rathi, Anuj K. ;
Nogueira, Isabel D. ;
Varma, Rajender S. ;
Branco, Paula S. .
GREEN CHEMISTRY, 2013, 15 (07) :1895-1899
[10]   Magnetically recyclable magnetite-ceria (Nanocat-Fe-Ce) nanocatalyst - applications in multicomponent reactions under benign conditions [J].
Gawande, Manoj B. ;
Bonifacio, Vasco D. B. ;
Varma, Rajender S. ;
Nogueira, Isabel D. ;
Bundaleski, Nenad ;
Ghumman, C. Amjad A. ;
Teodoro, Orlando M. N. D. ;
Branco, Paula S. .
GREEN CHEMISTRY, 2013, 15 (05) :1226-1231