Heteronuclear heavy alkenes E=E′ (E, E′ = group 14 elements):: Germasilenes, silastannenes, germastannenes...: Next stop?

被引：128
作者：
Lee, VY [1 ]
Sekiguchi, A [1 ]
机构：
[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
来源：
ORGANOMETALLICS | 2004年 / 23卷 / 12期
关键词：
D O I：
10.1021/om040027h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Recent advances in the chemistry of stable heteronuclear heavy alkenes >Edouble bondE'< (E, E' group 14 elements) are reviewed, covering silenes (>Sidouble bondC<), germenes (>Gedouble bondC<), stannenes (>Sndouble bondC<), germasilenes (>Gedouble bondSi<), silastannenes (>Sidouble bondSn<), and germastannenes (>Gedouble bondSn<). Their unique structures, bonding modes, and reactivities have been shown to be different from those of the homonuclear species, primarily due to the polarity of the >Edouble bondE'< bond resulting from the difference in the electronegativities of the doubly bonded atoms.
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收藏
页码：2822 / 2834
页数：13
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