Non-sensitized selective photochemical reduction of CO2 to CO under visible light with an iron molecular catalyst

被引：117

作者：

Rao, Heng ^{[1
]}

Bonin, Julien ^{[1
]}

Robert, Marc ^{[1
]}

机构：

[1] Univ Paris Diderot, Sorbonne Paris Cite, CNRS, Lab Electrochim Mol,UMR 7591, 15 Rue Jean Antoine de Baif, F-75205 Paris 13, France

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 19期

关键词：

PHOTOCATALYTIC REDUCTION; EFFICIENT; PHOTOREDUCTION; LUMINESCENCE; PORPHYRINS; CONVERSION; COBALT;

D O I：

10.1039/c6cc09967j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A substituted tetraphenyl iron porphyrin, bearing positively charged trimethylammonio groups at the para position of each phenyl ring, demonstrates its ability as a homogeneous molecular catalyst to selectively reduce CO2 to CO under visible light irradiation in organic media without the assistance of a sensitizer and no competitive hydrogen evolution for several days.

引用

页码：2830 / 2833

页数：4

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