Spectroscopic properties of Dy3+: Bi4Si3O12 single crystal

被引:55
作者
Zhang, Yan [1 ]
Xu, Jiayue [1 ]
Lu, Baoliang [2 ]
机构
[1] Shanghai Inst Technol, Sch Mat Sci & Engn, Shanghai 200235, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
关键词
Spectroscopic properties; Crystal growth; Dy3+:Bi4Si3O12; OPTICAL SPECTROSCOPY; ABSORPTION INTENSITIES; YELLOW LASER; EMISSION; IONS; TRANSITIONS; SPECTRA; SM3+; NM;
D O I
10.1016/j.jallcom.2013.08.090
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dy3+: Bi4Si3O12 crystal up to phi 25 x 110 mm(2) has been grown by the modified vertical Bridgman method. The absorption spectrum, excitation spectrum, emission spectrum and fluorescence decay curve of Dy3+: Bi4Si3O12 crystal were measured at room temperature. The spontaneous transition probabilities, the branching ratios and the radiative lifetimes have been calculated by means of the Judd-Ofelt theory and compared with the experimental results for the F-4(9/2) emitting level. The decay curve of Dy3+: Bi4Si3O12 crystal has been fitted with the Inokuti-Hirayama energy transfer model which revealed that electric dipole-dipole interaction is responsible for the energy transfer processes in Dy3+ ions doped Bi4Si3O12 crystal. (C) 2013 Elsevier B. V. All rights reserved.
引用
收藏
页码:635 / 639
页数:5
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