Comment on "Stabilization of Low-Valent Iron(I) in a High-Valent Vanadium(V) Oxide Cluster"

被引：5
作者：
Sproules, Stephen [1 ]
机构：
[1] Univ Glasgow, WestCHEM, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 30期
关键词：
density functional theory; electronic structure; iron; polyoxometalates; spectroscopy; POLYOXOMETALATE OXIDATION CATALYSTS; COMPLEXES; BOND; STATE; EPR; OXO; IDENTIFICATION; REACTIVITY; MOSSBAUER; LIGANDS;
D O I：
10.1002/anie.201811125
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A recent Communication in this journal reported the stabilization of low-valent iron(I) in a fully oxidized polyoxovanadate. With no ligand-field argument to support such an assignment, a re-evaluation of the data accompanied by detailed computational analysis reveals the redox chemistry is localized to the polyoxovanadate, and when reduced, instigates a spin transition at iron.
引用
收藏
页码：10043 / 10047
页数：5
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