Effect of poly(ethylene-co-vinyl acetate) additive on mechanical properties of maleic anhydride-grafted acrylonitrile butadiene styrene for coating applications

被引:12
作者
Olongal, Manaf [1 ]
Nainar, Mohamed Ansari Mohamed [2 ]
Marakkattupurathe, Manoj [1 ]
Asharaf, Shadiya Muslim Veettil [3 ]
Athiyanathil, Sujith [1 ]
机构
[1] Natl Inst Technol Calicut, Dept Chem, Mat Res Lab, Kozhikode, India
[2] Univ Tenaga Nas, Dept Mech Engn, Kajang, Malaysia
[3] Cochin Univ Sci & Technol, Dept Polymer Sci & Rubber Technol, Cochin, Kerala, India
关键词
REACTIVE COMPATIBILIZERS; FLAME-RETARDANT; G-MAH; BLENDS; MELT; NANOCOMPOSITES; POLYPROPYLENE; TERPOLYMER; MORPHOLOGY; POLYCARBONATE;
D O I
10.1002/vnl.21692
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The Izod impact strength of maleic anhydride-grafted acrylonitrile butadiene styrene (MA-g-ABS) copolymer has been improved by the use of rubbery poly(ethylene-co-vinyl acetate) (EVA). The MA-g-ABS is prepared by an internal mixer using dicumyl peroxide as free radical initiator, and the grafting degree was determined using back-titration method. The amount of EVA is optimized by evaluating the Izod impact strength, tensile, and flexural properties of the samples. Addition of 6% EVA into MA-g-ABS system improved the Izod impact strength and tensile strength by 18% and 35%, respectively. The miscibility of EVA in ABS and MA-g-ABS matrices has been observed using differential scanning calorimetry and scanning electron microscopy techniques. The enhanced adhesion property exhibited by MA-g-ABS/EVA systems promises it as a good candidate for thermoplastic coating applications on aluminum substrates. J. VINYL ADDIT. TECHNOL., 25:287-295, 2019. (c) 2018 Society of Plastics Engineers
引用
收藏
页码:287 / 295
页数:9
相关论文
共 40 条
[21]   Investigating Miscibility of Polymers and Its Impact on the Morphology, Thermal, and Mechanical Properties of Polymer Blends [J].
Marwat, Zafarullah Khan ;
Baloch, Musa Kaleem .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2015, 36 (10-11) :2755-2768
[22]   Study of the Properties of Compatibilized ABS/PA6 Blends Using Response Surface Methodology [J].
Mohammadian-Gezaz, Somayyeh ;
Ghasemi, Ismaeil ;
Oromiehie, Abdolrasosl .
JOURNAL OF VINYL & ADDITIVE TECHNOLOGY, 2009, 15 (03) :191-198
[23]  
Neher B., 2014, MAT SCI APPL, V56, P9
[24]  
Phil J.S., 2000, POLYM ENG SCI, V40, P1635
[25]   Degradation behavior and kinetic study of ABS polymer [J].
Polli, H. ;
Pontes, L. A. M. ;
Araujo, A. S. ;
Barros, Joana M. F. ;
Fernandes, V. J., Jr. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 95 (01) :131-134
[26]   Solvothermal preparation of maleic anhydride grafted onto acrylonitrile-butadiene-styrene terpolyrner (ABS) [J].
Qi, RR ;
Chen, ZF ;
Zhou, CX .
POLYMER, 2005, 46 (12) :4098-4104
[27]   Modification of acrylonitrile-butadiene-styrene terpolymer by graft copolymerization with maleic anhydride in the melt. II. Properties and phase behavior [J].
Qi, RR ;
Qian, JL ;
Chen, ZF ;
Jin, X ;
Zhou, CX .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (05) :2834-2839
[28]   Modification of acrylonitrile-butadiene-styrene terpolymer by grafting with maleic anhydride in the melt. I. Preparation and characterization [J].
Qi, RR ;
Qian, JL ;
Zhou, CX .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 90 (05) :1249-1254
[29]  
Raj M.M., 2014, INT J APPL SCI ENG R, V3, P512, DOI [10.6088/ijaser.030200023, DOI 10.6088/IJASER.030200023]
[30]   Grafting of maleic anhydride onto acrylonitrile-butadiene- styrene terpolymer: Synthesis and characterization [J].
Rao, BM ;
Rao, PR ;
Sreenivasulu, B .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 1999, 38 (05) :967-977