Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents

被引：1421

作者：

Lai, JT ^{[1
]}

Filla, D ^{[1
]}

Shea, R ^{[1
]}

机构：

[1] Noveon Inc, Brecksville, OH 44141 USA

来源：

MACROMOLECULES | 2002年 / 35卷 / 18期

关键词：

D O I：

10.1021/ma020362m

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An overview is given on an easy synthesis of carbonxyl-terminated trithiocarbonates. Telechelic carboxyl-terminated polymers are shown to be easily obtained when dicarboxyl trithocarbonate is employed. Bulk or solution polymerizations of alkyl acrylates, acrylic acid, and styrene are well-controlled. Some disproportionation at chain ends are observed with methyl methacrylate.

引用

页码：6754 / 6756

页数：3

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