Synthesis, spectroscopic characterization, and structure of closo-1,10-B10H3F22- and related fluorinated derivatives of B10H102-

被引：9

作者：

Ivanov, SV ^{[1
]}

Ivanova, SM ^{[1
]}

Miller, SM ^{[1
]}

Anderson, OP ^{[1
]}

Kuznetsov, NT ^{[1
]}

Solntsev, KA ^{[1
]}

Strauss, SH ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST GEN & INORGAN CHEM,MOSCOW 117907,RUSSIA

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1997年 / 62卷 / 08期

关键词：

decaborane; fluorinatio; N-fluoro reagents;

D O I：

10.1135/cccc19971310

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The treatment of salts of the B10H102- anion with the commercially available N-fluoro reagent 1-chloromethyl-4-fluoro-1, 4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F-TEDA) resulted in the formation of fluorinated derivatives of this ten-vertex borane dianion. The effects of changing the solvent, temperature, and reagent stoichiometry were studied. The derivatives 1-B10H9F2-, 2-B10H9F2-, 1,2-B10H8F22- 1,6-B10H8F22-, 1,10-B10H8F22-, and 1,2,10-B10H7F32- were examined by a combination of B-11 and F-19 NMR spectroscopy and by IR spectroscopy. The salt [Ph4P](2)[1,10-B10H8F2]. 3CH(2)Cl(2) was structurally characterized by single-crystal X-ray crystallography: C51H48B10Cl6F2P2, monoclinic, C2/c, a = 13.8134(9), b = 19.141(1), c = 21.136(1) Angstrom, beta = 91.546(1)degrees, Z = 4, T = -100 degrees C, R = 0.077.

引用

页码：1310 / 1324

页数：15

共 58 条

[41] CRYSTAL-STRUCTURES OF DIPYRIDINIOMETHANE MONOHALOGENOHYDRO-CLOSO-DECABORATES(2-), [(C5H5N)(2)CH2][2-XB(10)H(9)] X=CL, BR, I [J].

PREETZ, W ;

NACHTIGAL, C .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (10) :1632-1636

[42]

PREETZ W, 1984, Z NATURFORSCH B, V39, P6

[43]

PREETZ W, 1994, Z NATURFORSCH B, V49, P1809

[44]

SHELDRICK GM, 1994, SMART SAINT

[45]

SHELDRICK GM, 1994, SHELXTL VERS 5 03

[46]

Shriver D.F., 1986, MANIPULATION AIR SEN, V2nd

[47] ANTIPODAL SHIELDING EFFECTS IN BORON-11, C-13, AND PHOSPHORUS-31 NUCLEAR MAGNETIC-RESONANCE SPECTRA OF ICOSAHEDRAL CARBORANE DERIVATIVES [J].

SIEDLE, AR ;

BODNER, GM ;

GARBER, AR ;

BEER, DC ;

TODD, LJ .

INORGANIC CHEMISTRY, 1974, 13 (10) :2321-2323

[48]

SOLNTSEV KA, 1992, KOORDINATS KHIM+, V18, P340

[49] CHEMISTRY OF BORANES .25. REACTIONS OF BIS-LIGANDO AND MONO-LIGANDO DERIVATIVES OF DECABORANE WITH HYDROGEN HALIDES [J].

STIBR, B ;

PLESEK, J ;

HERMANEK, S .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1972, 37 (08) :2696-&

[50] ARACHNO-6,9-C2B8H14 DICARBABORANE AND ITS 1-MONOHALOGENATED AND 5-MONOHALOGENATED DERIVATIVES [J].

STIBR, B ;

JANOUSEK, Z ;

PLESEK, J ;

JELINEK, T ;

HERMANEK, S .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1987, 52 (01) :103-112

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