A highly efficient warm white light-emitting Eu2+-activated silicate host: another striking application of mesoporous silica

被引:21
作者
Gandhi, Sakthivel [1 ,2 ]
Thandavan, Kavitha [2 ]
Kwon, Bong-Joon [1 ]
Woo, Hyun-Joo [1 ]
Kim, Chang Hae [3 ]
Yi, SoungSoo [4 ]
Jeong, Jung Hyun [5 ]
Shin, Dong-Soo [6 ]
Jang, Kiwan [1 ]
机构
[1] Changwon Natl Univ, Dept Phys, Chang Won, South Korea
[2] SASTRA Univ, Ctr Nanotechnol & Adv Biomat, Thanjavur, India
[3] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305606, South Korea
[4] Silla Univ, Dept Elect Mat Engn, Pusan, South Korea
[5] Pukong Natl Univ, Dept Phys, Pusan, South Korea
[6] Changwon Natl Univ, Dept Chem, Chang Won, South Korea
基金
新加坡国家研究基金会;
关键词
ENERGY-TRANSFER; PHOSPHOR; DIODES; LUMINESCENCE; LATTICES; FUTURE; EU2+; RED;
D O I
10.1039/c4tc00711e
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study outlines a novel approach to the synthesis of an efficient yellow-emitting Sr0.975Ca0.975Eu0.05SiO4 phosphor with the adequate red spectral components. This was achieved by the use of a well-known silicate source, mesoporous silica. The findings showed that the synthesized phosphor gave a broad emission from blue to red, along with a stable emission color till 450 K and an emission decay time of 1 mu s. When the phosphor was fabricated using UV (400 nm) and blue LED (450 nm) chips, it promisingly generated warm white light at a color temperature < 4000 K and a color rendering index > 80.
引用
收藏
页码:6630 / 6636
页数:7
相关论文
共 33 条
[1]   Ce-Doped YAG Nanophosphor and Red Emitting CuInS2/ZnS Core/Shell Quantum Dots for Warm White Light-Emitting Diode with High Color Rendering Index [J].
Aboulaich, Abdelhay ;
Michalska, Martyna ;
Schneider, Raphael ;
Potdevin, Audrey ;
Deschamps, Jerome ;
Deloncle, Rodolphe ;
Chadeyron, Genevieve ;
Mahiou, Rachid .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (01) :252-258
[2]   FLUORESCENCE OF EU2+-ACTIVATED PHASES IN BINARY ALKALINE EARTH ORTHOSILICATE SYSTEMS [J].
BARRY, TL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1968, 115 (11) :1181-&
[3]   An Efficient, Thermally Stable Cerium-Based Silicate Phosphor for Solid State White Lighting [J].
Brgoch, Jakoah ;
Borg, Christopher K. H. ;
Denault, Kristin A. ;
Mikhailovsky, Alexander ;
DenBaars, Steven P. ;
Seshadri, Ram .
INORGANIC CHEMISTRY, 2013, 52 (14) :8010-8016
[4]   ORDER-DISORDER IN THE ALPHA'-(CA,SR)2SIO4 SOLID-SOLUTION - A STRUCTURAL AND STATISTICAL-THERMODYNAMIC ANALYSIS [J].
CATTI, M ;
GAZZONI, G ;
IVALDI, G .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1984, 40 (DEC) :537-544
[5]   Solvothermal synthesis of red and green emitting Ca1.65Sr0.35SiO4:Eu3+ and Ca1.65Sr0.35SiO4:Eu2+ phosphors for solid-state lighting applications [J].
Gandhi, Sakthivel ;
Thandavan, Kavitha ;
Kwon, Bong-Joon ;
Woo, Hyun-Joo ;
Jang, Kiwan ;
Shin, Dong-Soo .
CERAMICS INTERNATIONAL, 2014, 40 (04) :5245-5254
[6]   Mesoporous silica: a highly promising and compatible candidate for optical and biomedical applications [J].
Gandhi, Sakthivel ;
Thandavan, Kavitha ;
Kwon, Bong-Joon ;
Woo, Hyun-Joo ;
Yi, Soung Soo ;
Lee, Ho Sueb ;
Jeong, Jung Hyun ;
Jang, Kiwan ;
Shin, Dong Soo .
RSC ADVANCES, 2014, 4 (12) :5953-5962
[7]   Superparamagnetic nanosystems based on iron oxide nanoparticles & mesoporous silica: synthesis & evaluation of their magnetic, relaxometric and biocompatability properties [J].
Gandhi, Sakthivel ;
Venkatesh, S. ;
Sharma, Uma ;
Jagannathan, Naranamanglam R. ;
Sethuraman, Swaminathan ;
Krishnan, Uma Maheswari .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (39) :15698-15707
[8]   Influence of polyhydric solvents on the catalytic & adsorption properties of self-oriented mesoporous SBA-15 silica [J].
Gandhi, Sakthivel ;
Sethuraman, Swaminathan ;
Krishnan, Uma Maheswari .
JOURNAL OF POROUS MATERIALS, 2011, 18 (03) :329-336
[9]   Extrahigh color rendering white light-emitting diode lamps using oxynitride and nitride phosphors excited by blue light-emitting diode [J].
Kimura, Naoki ;
Sakuma, Ken ;
Hirafune, Syunichiro ;
Asano, Kenichiro ;
Hirosaki, Naoto ;
Xie, Rong-Jun .
APPLIED PHYSICS LETTERS, 2007, 90 (05)
[10]   Status and future of high-power light-emitting diodes for solid-state lighting [J].
Krames, Michael R. ;
Shchekin, Oleg B. ;
Mueller-Mach, Regina ;
Mueller, Gerd O. ;
Zhou, Ling ;
Harbers, Gerard ;
Craford, M. George .
JOURNAL OF DISPLAY TECHNOLOGY, 2007, 3 (02) :160-175