MOCVD-loading of mesoporous siliceous matrices with Cu/ZnO:: Supported catalysts for methanol synthesis

被引：52

作者：

Becker, R ^{[1
]}

Parala, H ^{[1
]}

Hipler, F ^{[1
]}

Tkachenko, OP ^{[1
]}

Klementiev, KV ^{[1
]}

Grünert, W ^{[1
]}

Wilmer, H ^{[1
]}

Hinrichsen, O ^{[1
]}

Birkner, A ^{[1
]}

Muhler, M ^{[1
]}

Wöll, C ^{[1
]}

Schäfer, S ^{[1
]}

Fisher, RA ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44870 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 21期

关键词：

copper; CVD (chemical vapor deposition); heterogeneous catalysis; mesoporous materials; methanol synthesis; zinc oxide;

D O I：

10.1002/anie.200351166

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Consecutive vaporization cycles for the preparation of heterogeneous catalysts: Active Cu- and ZnO-containing methanol-synthesis catalysts were obtained by vaporizing suitable organometallic precursors into mesoporous silicates, followed by thermal treatment (see scheme). The catalytically active components in the final material have nanoscopic dimensions. The methanol production by the catalysts is similar to that of systems synthesized by the classical route.

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页码：2839 / 2842

页数：4

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